Thermally stable polymers, method of preparation, and articles made therefrom

ABSTRACT

The present invention provides compositions comprising (a) a thermally stable polymer comprising resorcinol arylate polyester chain members substantially free of anhydride linkages linking at least two mers of the polymer chain, and (b) at least one auxiliary stabilizer additive selected from the group consisting of 2,2′-(1,4-phenylene)bis(4H-3,1-benzoxazin-4-one) and 1,3-bis[(2-cyano-3,3-diphenylacryloyl)oxy]-2,2-bis[[(2-cyano-3,3-diphenylacryloyl)oxy]methyl]propane. Both multilayer and unitary articles comprising the composition are also provided.

CROSS-REFERENCE TO RELATED APPLICATION

[0001] This application is a continuation-in-part of copending U.S. application Ser. No. 09/908,396, filed Jul. 18, 2001, which is a continuation-in-part of U.S. application Ser. No. 09/368,706, filed Aug. 5, 1999, now U.S. Pat. No. 6,306,507, which claims the benefit of U.S. Provisional Application No. 60/134,692, filed May 18, 1999, and which applications are incorporated herein by reference.

BACKGROUND OF THE INVENTION

[0002] This invention relates to thermally stable polymers comprising polyester chain members derived from at least one 1,3-dihydroxybenzene moiety and at least one aromatic dicarboxylic acid moiety (often referred to hereinafter as resorcinol arylate chain members), a method for their preparation, and multilayer articles made therefrom.

[0003] Various polymeric articles have a problem of long term color instability. In many cases this instability is seen as yellowing of the polymer, detracting from its attractiveness and also transparency when the polymer was initially transparent. Loss of gloss can also be an undesirable long term phenomenon.

[0004] Yellowing of polymers is often caused by the action of ultraviolet radiation, and such yellowing is frequently designated “photoyellowing”. Numerous means for suppressing photoyellowing have been employed and proposed. Many of these involve incorporation in the polymer of ultraviolet absorbing compounds (UVA's). For the most part, UVA's are low molecular weight compounds, which must be employed at relatively low levels, typically up to 1% by weight, to avoid degradation of the physical properties of the polymer such as impact strength and high temperature properties as reflected in heat distortion temperature. Another problem of concern with polymers such as aromatic polycarbonates and addition polymers of alkenylaromatic compounds such as styrene is susceptibility to attack by organic liquids.

[0005] One way of protecting a resinous article against photoyellowing and loss of gloss is to apply a coating of a weatherable second polymer, the term “weatherable” as used herein signifying resistance to such phenomena. Coatings made from polyesters containing resorcinol arylate units often possess good weatherability properties. The arylate moieties typically contain isophthalate, terephthalate, and especially mixtures of iso- and terephthalate units. Polyesters of resorcinol with mixtures of isophthalate and terephthalate chain members typically have good weatherability properties and may provide protection against photoyellowing when coated over a resinous substrate.

[0006] The good weatherability properties of polyesters containing resorcinol arylate units are believed to arise in large part from the screening effect said polymers may provide to ultraviolet (UV) light. On exposure to UV light polymers comprising resorcinol arylate chain members may undergo photochemical Fries rearrangement converting at least a portion of the polymer from polyester chain members to o-hydroxybenzophenone-type chain members. The o-hydroxybenzophenone-type chain members act to screen further UV light and protect UV-sensitive components in a resorcinol arylate-containing composition. The good weatherability properties of polymers comprising resorcinol arylate chain members make them especially useful in blends and in multilayer articles in which said polymers may act as a protecting layer for more sensitive substrate components.

[0007] Copolyesters comprising resorcinol iso- and terephthalate polyester chain members in combination with diacid or diol alkylene chain members (so-called “soft-block” chain members) are disclosed in commonly owned U.S. Pat. No. 5,916,997. These copolymers have excellent weatherability and flexibility. Copolyestercarbonates comprising resorcinol iso- and terephthalate polyester chain members in combination with carbonate chain members are disclosed in commonly owned, co-pending application Ser. No. 09/416,529, filed Oct. 12, 1999. These copolymers have excellent weatherability and are compatible with polycarbonates in blends.

[0008] Polyesters containing resorcinol arylate chain members have been prepared by melt methods as disclosed in U.S. Pat. No. 4,127,560 and in Japanese Kokai 1/201,326. The methods may provide polyesters containing isophthalate and terephthalate chain members but do not allow the incorporation of greater than 30 mole % terephthalate. In addition, the polyesters obtained have unacceptable color.

[0009] Polyesters containing resorcinol arylate chain members have also been prepared by an interfacial method. The interfacial method comprises a solvent mixture containing water and at least one organic solvent substantially immiscible with water. According to U.S. Pat. No. 3,460,961 and Eareckson, Journal of Polymer Science, vol. XL, pp. 399-406 (1959), preparation of resorcinol arylate polyesters with a mixture of iso- and terephthalate chain members is performed by an interfacial method in water and a water-immiscible solvent such as chloroform or dichloromethane using 1:1 stoichiometric ratio of resorcinol to either iso- or terephthaloyl dichloride; or a mixture thereof, in the presence of aqueous sodium hydroxide. The resorcinol is combined with the aqueous sodium hydroxide before addition of acid chlorides, and the reaction is run at pH which is initially high but which decreases as the reaction proceeds. The molecular weight of the polymers is not controlled. The method provides polymer with very high weight average molecular weight (Mw), making the polymer unsuitable for some applications. Furthermore, the polymer has poor thermal stability and loses molecular weight upon thermal treatment.

[0010] Multilayer articles containing layers made from resorcinol arylate-containing polyester have been described by Cohen et al., Journal of Polymer Science: Part A-1, vol. 9, 3263-3299 (1971) and in U.S. Pat. No. 3,460,961. The polyester was made either in solution or by an interfacial process. The solution method requires the use of a stoichiometric amount of an organic base, such as a tertiary amine, which must be isolated and recovered for reuse in any economical, environmentally friendly process. Both methods produce thermally unstable polyester which can only be applied by solution coating followed by evaporation of the solvent to make a multilayer article. This solution coating method has numerous deficiencies, some of which are mentioned in the Cohen et al. paper at page 3267: namely, the necessity to use high priced and toxic solvents, the inherently low concentration of the arylate polymer in the solvent and the tendency of the solutions to gel. Accordingly, the described polyesters were considered “unacceptable coating candidates”.

[0011] Japanese Kokai 1/199,841 discloses articles having a substrate layer comprising at least 90 mole percent poly(ethylene terephthalate) and a gas barrier coating layer which is a polyester of resorcinol and a minimum of 50 mole % isophthalic acid, optionally with copolyester units derived from another dicarboxylic acid such as terephthalic acid, naphthalenedicarboxylic acid or various other specifically named dicarboxylic acids. The disclosed articles may be prepared by a series of operations including co-injection molding. However, the only types of articles disclosed are bottles, which are produced from a co-injection molded parison by subsequent blow molding. Larger articles, such as external automobile body parts, are not disclosed and no method for their production is suggested, nor are articles in which the substrate layer is anything other than poly(ethylene terephthalate). In addition, the resorcinol isophthalate polyesters were prepared either by melt methods which do not allow the incorporation of greater than 30 mole % terephthalate and give polyester with unacceptable color, or by the interfacial method which produces thermally unstable polyester.

[0012] It remains of interest, therefore, to develop a method for preparing weatherable, solvent resistant multilayer articles which are capable of use for such varied purposes as body parts for outdoor vehicles and devices such as automobiles. There is also a particular need for polymers comprising resorcinol arylate chain members having controlled molecular weight, high thermal stability, and low color. There is also a particular need for polymers comprising resorcinol arylate chain members that can be processed using typical melt processing techniques.

BRIEF SUMMARY OF THE INVENTION

[0013] The present inventors have identified the primary source of poor thermal stability in polymers comprising resorcinol arylate polyester chain members prepared by the interfacial method, and have discovered a method to prepare said polymers in thermally stable form with controlled molecular weight. The new method also allows the preparation of virtually colorless polymers comprising resorcinol arylate polyester chain members.

[0014] In one of its aspects the present invention provides a composition comprising (a) a thermally stable polymer comprising resorcinol arylate polyester chain members substantially free of anhydride linkages linking at least two mers of the polymer chain, and (b) at least one auxiliary stabilizer additive selected from the group consisting of 2,2′-(1,4-phenylene)bis(4H-3,1-benzoxazin-4-one) and 1,3-bis[(2-cyano-3,3-diphenylacryloyl)oxy]-2,2-bis[[(2-cyano-3,3-diphenylacryloyl)oxy]methyl]propane.

[0015] In another of its aspects the present invention, provides a composition comprising (a) a thermally stable polymer consisting essentially of resorcinol arylate polyester chain members substantially free of anhydride linkages linking at least two mers of the polymer chain, and (b) at least one auxiliary stabilizer additive selected from the group consisting of 2,2′-(1,4-phenylene)bis(4H-3,1-benzoxazin-4-one) and 1,3-bis[(2-cyano-3,3-diphenylacryloyl)oxy]-2,2-bis[[(2-cyano-3,3-diphenylacryloyl)oxy]methyl]propane.

[0016] In another of its aspects the present invention provides a composition comprising (a) a thermally stable copolymer comprising resorcinol arylate polyester chain members in combination with C₃₋₂₀ straight chain alkylene, C₃₋₁₀ branched alkylene, or C₄₋₁₀ cyclo- or bicyclo-alkylene chain members, substantially free of anhydride linkages linking at least two mers of the polymer chain, and (b) at least one auxiliary stabilizer additive selected from the group consisting of 2,2′-(1,4-phenylene)bis(4H-3,1-benzoxazin-4-one) and 1,3-bis[(2-cyano-3,3-diphenylacryloyl)oxy]-2,2-bis[[(2-cyano-3,3-diphenylacryloyl)oxy]methyl]propane.

[0017] In another of its aspects the present invention provides a composition comprising (a) a thermally stable block copolymer comprising resorcinol arylate polyester segments in combination with organic carbonate segments, substantially free of anhydride linkages linking at least two mers of the polymer chain, and (b) at least one auxiliary stabilizer additive selected from the group consisting of 2,2′-(1,4-phenylene)bis(4H-3,1-benzoxazin-4-one) and 1,3-bis[(2-cyano-3,3-diphenylacryloyl)oxy]-2,2-bis[[(2-cyano-3,3-diphenylacryloyl)oxy]methyl]propane.

[0018] In yet another of its aspects the present invention provides articles comprising (a) a thermally stable polymer comprising resorcinol arylate polyester chain members substantially free of anhydride linkages linking at least two mers of the polymer chain, and (b) at least one auxiliary stabilizer additive selected from the group consisting of 2,2′-(1,4-phenylene)bis(4H-3,1-benzoxazin-4-one) and 1,3-bis[(2-cyano-3,3-diphenylacryloyl)oxy]-2,2-bis[[(2-cyano-3,3-diphenylacryloyl)oxy]methyl]propane.

BRIEF DESCRIPTION OF THE DRAWINGS

[0019]FIG. 1 shows a graph of delta E vs. exposure in CIRA/sodalime xenon arc lamp for a molded disk containing UVINUL 3030 and a resorcinol arylate block copolymer with bisphenol A polycarbonate containing about 10 wt. % carbonate units, the disk comprising a layer of copolymer laminated onto a layer of white bisphenol A polycarbonate.

[0020]FIG. 2 shows a graph of delta E vs. exposure in boro/boro xenon arc lamp for a molded disk containing CYASORB UV-3638 and a resorcinol arylate block copolymer with bisphenol A polycarbonate containing about 20 wt. % carbonate units, the disk comprising a layer of copolymer laminated onto a layer of white bisphenol A polycarbonate.

DETAILED DESCRIPTION OF THE INVENTION

[0021] In one embodiment the present invention comprises an interfacial method for preparing thermally stable polymers comprising resorcinol arylate polyester chain members which derive their thermal stability in large part from being substantially free of anhydride linkages in the polymer chains. In another embodiment the present invention comprises the thermally stable polymers prepared by such an interfacial method.

[0022] Thermal stability within the context of the present invention refers to resistance of a polymer to molecular weight degradation under thermal conditions. Thus, a polymer with poor thermal stability shows significant molecular weight degradation under thermal conditions, such as during extrusion, molding, thermoforming, hot-pressing, and like conditions. Molecular weight degradation may also be manifest through color formation and/or in the degradation of other properties such as weatherability, gloss, mechanical properties, and/or thermal properties. Molecular weight degradation can also cause significant variation in processing conditions as the melt viscosity changes.

[0023] In one of its aspects the method of the present invention provides thermally stable polymers comprising arylate polyester chain members. Said chain members comprise at least one diphenol residue in combination with at least one aromatic dicarboxylic acid residue. In one embodiment the diphenol residue is derived from a 1,3-dihydroxybenzene moiety, as illustrated in Formula I, commonly referred to throughout this specification as resorcinol or resorcinol moiety. Resorcinol or resorcinol moiety as used within the context of the present invention should be understood to include both unsubstituted 1,3-dihydroxybenzene and substituted 1,3-dihydroxybenzenes unless explicitly stated otherwise.

[0024] In Formula I R is at least one of C₁₋₁₂ alkyl or halogen, and n is 0-3.

[0025] Suitable dicarboxylic acid residues include aromatic dicarboxylic acid residues derived from monocyclic moieties. In various embodiments suitable dicarboxylic acid residues include those derived from isophthalic acid, terephthalic acid, or mixtures of isophthalic and terephthalic acids. Suitable dicarboxylic acid residues also include those derived from polycyclic moieties, illustrative examples of which include diphenyl dicarboxylic acid, diphenylether dicarboxylic acid, and naphthalenedicarboxylic acid, especially naphthalene-2,6-dicarboxylic acid. In some embodiments the aromatic dicarboxylic acid residues are derived from mixtures of isophthalic and/or terephthalic acids as typically illustrated in Formula II.

[0026] Therefore, in one embodiment the present invention provides thermally stable polymers comprising resorcinol arylate polyester chain members as typically illustrated in Formula III wherein R and n are as previously defined:

[0027] Previous interfacial methods for preparing polyesters comprising resorcinol arylate chain members typically provide polymers with poor thermal stability and uncontrolled molecular weight. The present inventors have discovered that a primary reason for poor thermal stability is the presence of anhydride linkages in the backbone of the polyester chain. Typical anhydride linkages are illustrated in Formula IV. Such anhydride linkages link at least two mers in a polymer chain and may arise through combination of two isophthalate or terephthalate moieties or mixtures thereof, although it is to be understood that anhydride linkages in polymers comprising resorcinol arylate chain members may arise through combination of any suitable similar dicarboxylic acid residues or mixtures of suitable dissimilar dicarboxylic acid residues present in a reaction mixture.

[0028] Although the invention is not limited by theory, it is believed that the anhydride linkage represents a weak bond in the polyester chain, which can break under thermal processing conditions to produce shorter chains terminated by acid end-groups. These acid end-groups, in turn, may accelerate the hydrolysis of the arylate moiety, generating additional carboxyl and hydroxyl end-groups, and further contributing to the molecular weight degradation, and loss in other desirable properties. Anhydride linkages may arise through several mechanisms. In one mechanism a carboxylic acid chloride may be hydrolyzed to carboxylic acid when the esterification reaction is run at high pH. The carboxylic acid or corresponding carboxylate may then react with another carboxylic acid chloride to yield an anhydride linkage.

[0029] Anhydride linkages may be detected by means known to those skilled in the art such as by ¹³C nuclear magnetic resonance spectroscopy (NMR). For example, resorcinol arylate polyesters comprising dicarboxylic acid residues derived from a mixture of iso- and terephthalic acids typically show ¹³C NMR resonances attributed to anhydride at 161.0 and 161.1 ppm (in deuterochloroform relative to tetramethylsilane), as well as resonances for the polymer carboxylic acid and hydroxyl end-groups. After thermal processing (for example, extrusion and/or molding), the polymer molecular weight decreases, and the anhydride resonances typically decrease, while those of the acid and hydroxyl end-groups typically increase.

[0030] Anhydride linkages in polymers comprising resorcinol arylate polyester chain members may also be detected by reaction of polymer with a nucleophile, such as a secondary amine. For example, resorcinol arylate polyesters comprising dicarboxylic acid residues derived from a mixture of iso- and terephthalic acids can be dissolved in a convenient solvent, such as dichloromethane, and treated with a secondary amine, such as dibutylamine or diisobutylamine, for several minutes at ambient temperature. Comparison of the starting polymer molecular weight to that after amine treatment typically shows a decrease in molecular weight which can be correlated with the corresponding decrease observed under typical thermal processing conditions. Although the invention is not meant to be limited by theory, it is believed that nucleophiles, such as secondary amine and phenolic, attack anhydride linkages (as opposed to ester linkages) selectively under the reaction conditions. The decrease in molecular weight upon reaction with amine nucleophile is therefore an indication of the presence of anhydride functionality in the polymer.

[0031] In one of its aspects the present invention provides an interfacial method for preparing polymers comprising resorcinol arylate polyester chain members substantially free of anhydride linkages, said method comprising a first step of combining at least one resorcinol moiety and at least one catalyst in a mixture of water and at least one organic solvent substantially immiscible with water. Suitable resorcinol moieties comprise units of Formula V:

[0032] wherein R is at least one of C₁₋₁₂ alkyl or halogen, and n is 0-3. Alkyl groups, if present, are typically straight-chain, branched, or cyclic alkyl groups, and are most often located in the ortho position to both oxygen atoms although other ring locations are contemplated. Suitable C₁₋₁₂ alkyl groups include, but are not limited to, methyl, ethyl, n-propyl, isopropyl, butyl, iso-butyl, t-butyl, hexyl, cyclohexyl, nonyl, decyl, and aryl-substituted alkyl, including benzyl. In a particular embodiment an alkyl group is methyl. Suitable halogen groups are bromo, chloro, and fluoro. The value for n in various embodiments may be 0-3, in some embodiments 0-2, and in still other embodiments 0-1. In one embodiment a resorcinol moiety is 2-methylresorcinol. In another embodiment the resorcinol moiety is an unsubstituted resorcinol moiety in which n is zero.

[0033] The method further comprises combining at least one catalyst with the reaction mixture. Said catalyst may be present in various embodiments at a total level of 0.1 to 10 mole %, and in some embodiments at a total level of 0.2 to 6 mole % based on total molar amount of acid chloride groups. Suitable catalysts comprise tertiary amines, quaternary ammonium salts, quaternary phosphonium salts, hexaalkylguanidinium salts, and mixtures thereof. Suitable tertiary amines include triethylamine, dimethylbutylamine, diisopropylethylamine, 2,2,6,6-tetramethylpiperidine, and mixtures thereof. Other contemplated tertiary amines include N—C₁-C₆-alkyl-pyrrolidines, such as N-ethylpyrrolidine, N—C₁-C₆-piperidines, such as N-ethylpiperidine, N-methylpiperidine, and N-isopropylpiperidine, N—C₁-C₆-morpholines, such as N-ethylmorpholine and N-isopropyl-morpholine, N—C₁-C₆-dihydroindoles, N—C₁-C₆-dihydroisoindoles, N—C₁-C₆-tetrahydroquinolines, N—C₁-C₆-tetrahydroisoquinolines, N—C₁-C₆-benzo-morpholines, 1-azabicyclo-[3.3.0]-octane, quinuclidine, N—C₁-C₆-alkyl-2-azabicyclo-[2.2.1]-octanes, N—C₁-C₆-alkyl-2-azabicyclo-[3.3.1]-nonanes, and N—C₁-C₆-alkyl-3-azabicyclo-[3.3.1]-nonanes, N,N,N′,N′-tetraalkylalkylene-diamines, including N,N,N′,N′-tetraethyl-1,6-hexanediamine. In various embodiments tertiary amines are triethylamine and N-ethylpiperidine.

[0034] When the catalyst consists of at least one tertiary amine alone, then said catalyst may be present in one embodiment at a total level of 0.1 to 10 mole %, in another embodiment at a total level of 0.2 to 6 mole %, in another embodinlent at a total level of 1 to 4 mole %, and in still another embodiment at a total level of 2.5 to 4 mole % based on total molar amount of acid chloride groups. In one embodiment of the invention all of the at least one tertiary amine is present at the beginning of the reaction before addition of dicarboxylic acid dichloride to resorcinol moiety. In another embodiment a portion of any tertiary amine is present at the beginning of the reaction and a portion is added following or during addition of dicarboxylic acid dichloride to resorcinol moiety. In this latter embodiment the amount of any tertiary amine initially present with resorcinol moiety may range in one embodiment from about 0.005 wt. % to about 10 wt. %, in another embodiment from about 0.01 to about 1 wt. %, and in still another embodiment from about 0.02 to about 0.3 wt. % based on total amine.

[0035] Suitable quaternary ammonium salts, quaternary phosphonium salts, and hexaalkylguanidinium salts include halide salts such as tetraethylammonium bromide, tetraethylammonium chloride, tetrapropylammonium bromide, tetrapropylammonium chloride, tetrabutylammonium bromide, tetrabutylammonium chloride, methyltributyl ammonium chloride, benzyltributylammonium chloride, benzyltriethylammonium chloride, benzyltrimethylammonium chloride, trioctylmethylammonium chloride, cetyldimethylbenzylammonium chloride, octyltriethylammonium bromide, decyltriethylammonium bromide, lauryltriethylammonium bromide, cetyltrimethylammonium bromide, cetyltriethylammonium bromide, N-laurylpyridinium chloride, N-laurylpyridinium bromide, N-heptylpyridinium bromide, tricaprylylmethylammonium chloride (sometimes known as ALIQUAT 336), methyltri-C₈-C₁₀-alkyl-ammonium chloride (sometimes known as ADOGEN 464), N,N,N′,N′,N′-pentaalkyl-alpha, omega-amine-ammonium salts such as disclosed in U.S. Pat. No. 5,821,322; tetrabutylphosphonium bromide, benzyltriphenylphosphonium chloride, triethyloctadecylphosphonium bromide, tetraphenylphosphonium bromide, triphenylmethylphosphonium bromide, trioctylethylphosphonium bromide, cetyltriethylphosphonium bromide, hexaalkylguanidinium halides, hexaethylguanidinium chloride, and the like, and mixtures thereof.

[0036] Organic solvents substantially immiscible with water include those which in one embodiment are less than about 5 wt. %, and in another embodiment less than about 2 wt. % soluble in water under the reaction conditions. Suitable organic solvents include dichloromethane, trichloroethylene, tetrachloroethane, chloroform, 1,2-dichloroethane, toluene, xylene, trimethylbenzene, chlorobenzene, o-dichlorobenzene, and mixtures thereof. In a particular embodiment the solvent is dichloromethane.

[0037] Suitable dicarboxylic acid dichlorides may comprise aromatic dicarboxylic acid dichlorides derived from monocyclic moieties, illustrative examples of which include isophthaloyl dichloride, terephthaloyl dichloride, or mixtures of isophthaloyl and terephthaloyl dichlorides. Suitable dicarboxylic acid dichlorides may also comprise aromatic dicarboxylic acid dichlorides derived from polycyclic moieties, illustrative examples of which include diphenyl dicarboxylic acid dichloride, diphenylether dicarboxylic acid dichloride, and naphthalenedicarboxylic acid dichloride, especially naphthalene-2,6-dicarboxylic acid dichloride; or from mixtures of monocyclic and polycyclic aromatic dicarboxylic acid dichlorides. In one embodiment the dicarboxylic acid dichloride comprises mixtures of isophthaloyl and/or terephthaloyl dichlorides as typically illustrated in Formula VI.

[0038] Either or both of isophthaloyl and terephthaloyl dichlorides may be present. In some embodiments the dicarboxylic acid dichlorides comprise mixtures of isophthaloyl and terephthaloyl dichloride in a molar ratio of isophthaloyl to terephthaloyl of about 0.25-4.0:1; in other embodiments the molar ratio is about 0.4-2.5:1; and in still other embodiments the molar ratio is about 0.67-1.5:1.

[0039] The pH of the reaction mixture is maintained in some embodiments between about 3 and about 8.5, and in other embodiments between about 5 and about 8, throughout addition of the at least one dicarboxylic acid dichloride to the at least one resorcinol moiety. Suitable reagents to maintain the pH include alkali metal hydroxides, alkaline earth hydroxides, and alkaline earth oxides. In some embodiments the reagents are potassium hydroxide and sodium hydroxide. In a particular embodiment the reagent is sodium hydroxide. The reagent to maintain pH may be included in the reaction mixture in any convenient form. In some embodiments said reagent is added to the reaction mixture as an aqueous solution simultaneously with the at least one dicarboxylic acid dichloride.

[0040] The temperature of the reaction mixture may be any convenient temperature that provides a rapid reaction rate and a resorcinol arylate-containing polymer substantially free of anhydride linkages. Convenient temperatures include those from about −20° C. to the boiling point of the water-organic solvent mixture under the reaction conditions. In one embodiment the reaction is performed at the boiling point of the organic solvent in the water-organic solvent mixture. In another embodiment the reaction is performed at the boiling point of dichloromethane.

[0041] The total molar amount of acid chloride groups added to the reaction mixture is stoichiometrically deficient relative to the total molar amount of phenolic groups. Said stoichiometric ratio is desirable so that hydrolysis of acid chloride groups is minimized, and so that nucleophiles such as phenolic and/or phenoxide may be present to destroy any adventitious anhydride linkages, should any form under the reaction conditions. The total molar amount of acid chloride groups includes the at least one dicarboxylic acid dichloride, and any mono-carboxylic acid chloride chain-stoppers and any tri- or tetra-carboxylic acid tri- or tetra-chloride branching agents which may be used. The total molar amount of phenolic groups includes resorcinol moieties, and any mono-phenolic chain-stoppers and any tri- or tetra-phenolic branching agents which may be used. The stoichiometric ratio of total phenolic groups to total acid chloride groups is in one embodiment about 1.5-1.01:1 and in another embodiment about 1.2-1.02:1.

[0042] The presence or absence of adventitious anhydride linkages following complete addition of the at least one dicarboxylic acid dichloride to the at least one resorcinol moiety will typically depend upon the exact stoichiometric ratio of reactants and the amount of catalyst present, as well as other variables. For example, if a sufficient molar excess of total phenolic groups is present, anhydride linkages are often found to be absent. In one embodiment a molar excess of at least about 1% and in another embodiment a molar excess of at least about 3% of total amount of phenolic groups over total amount of acid chloride groups may suffice to eliminate anhydride linkages under the reaction conditions. When anhydride linkages may be present, it is often desirable that the final pH be greater than 7 so that nucleophiles such as phenolic, phenoxide and/or hydroxide may be present to destroy any adventitious anhydride linkages. Therefore, in various embodiments the method of the invention may further comprise the step of adjusting the pH of the reaction mixture in one embodiment to between 7 and 12, in another embodiment to between 8 and 12, and in still another embodiment to between 8.5 and 12, following complete addition of the at least one dicarboxylic acid dichloride to the at least one resorcinol moiety. The pH may be adjusted by any convenient method; in one embodiment the pH is adjusted using an aqueous base such as aqueous sodium hydroxide.

[0043] Provided the final pH of the reaction mixture is greater than 7, the method of the invention in another embodiment may further comprise the step of stirring the reaction mixture for a time sufficient to destroy completely any adventitious anhydride linkages, should any be present. The necessary stirring time will depend upon reactor configuration, stirrer geometry, stirring rate, temperature, total solvent volume, organic solvent volume, anhydride concentration, pH, and other factors. In some instances the necessary stirring time is essentially instantaneous, for example within seconds of pH adjustment to above 7, assuming any adventitious anhydride linkages were present to begin with. For typical laboratory scale reaction equipment a stirring time may be required in one embodiment of at least about 3 minutes, and in another embodiment of at least about 5 minutes. By this process nucleophiles, such as phenolic, phenoxide and/or hydroxide, may have time to destroy completely any adventitious anhydride linkages, should any be present.

[0044] At least one chain-stopper (also referred to sometimes hereinafter as capping agent) may also be present in the method and compositions of the invention. A purpose of adding at least one chain-stopper is to limit the molecular weight of polymer comprising resorcinol arylate polyester chain members, thus providing polymer with controlled molecular weight and favorable processability. Typically, at least one chain-stopper is added when the resorcinol arylate-containing polymer is not required to have reactive end-groups for further application. In the absence of chain-stopper resorcinol arylate-containing polymer may be either used in solution or recovered from solution for subsequent use such as in copolymer formation which may require the presence of reactive end-groups, typically hydroxy, on the resorcinol-arylate polyester segments. A chain-stopper may be at least one of mono-phenolic compounds, mono-carboxylic acid chlorides, and/or mono-chloroformates. Typically, the at least one chain-stopper may be present in quantities of 0.05 to 10 mole %, based on resorcinol moieties in the case of mono-phenolic compounds and based on acid dichlorides in the case mono-carboxylic acid chlorides and/or mono-chloroformates.

[0045] Suitable mono-phenolic compounds include monocyclic phenols, such as phenol, C₁-C₂₂ alkyl-substituted phenols, p-cumyl-phenol, p-tertiary-butyl phenol, hydroxy diphenyl; monoethers of diphenols, such as p-methoxyphenol. Alkyl-substituted phenols include those with branched chain alkyl substituents having 8 to 9 carbon atoms, preferably in which about 47 to 89% of the hydrogen atoms are part of methyl groups as described in U.S. Pat. No. 4,334,053. For some embodiments a mono-phenolic UV absorber is used as capping agent. Such compounds include 4-substituted-2-hydroxybenzophenones and their derivatives, aryl salicylates, monoesters of diphenols, such as resorcinol monobenzoate, 2-(2-hydroxyaryl)-benzotriazoles and their derivatives, 2-(2-hydroxyaryl)-1,3,5-triazines and their derivatives, and like compounds. In some embodiments mono-phenolic chain-stoppers are phenol, p-cumylphenol, and resorcinol monobenzoate.

[0046] Suitable mono-carboxylic acid chlorides include monocyclic, mono-carboxylic acid chlorides, such as benzoyl chloride, C₁-C₂₂ alkyl-substituted benzoyl chloride, toluoyl chloride, halogen-substituted benzoyl chloride, bromobenzoyl chloride, cinnamoyl chloride, 4-nadimidobenzoyl chloride, and mixtures thereof; polycyclic, mono-carboxylic acid chlorides, such as trimellitic anhydride chloride, and naphthoyl chloride; and mixtures of monocyclic and polycyclic mono-carboxylic acid chlorides. The chlorides of aliphatic monocarboxylic acids with up to 22 carbon atoms are also suitable. Functionalized chlorides of aliphatic monocarboxylic acids, such as acryloyl chloride and methacryoyl chloride, are also suitable. Suitable mono-chloroformates include monocyclic, mono-chloroformates, such as phenyl chloroformate, alkyl-substituted phenyl chloroformate, p-cumyl phenyl chloroformate, toluene chloroformate, and mixtures thereof.

[0047] A chain-stopper can be combined together with the resorcinol moieties, can be contained in the solution of dicarboxylic acid dichlorides, or can be added to the reaction mixture after production of a precondensate. If mono-carboxylic acid chlorides and/or mono-chloroformates are used as chain-stoppers, they are often introduced together with dicarboxylic acid dichlorides. These chain-stoppers can also be added to the reaction mixture at a moment when the chlorides of dicarboxylic acid have already reacted substantially or to completion. If phenolic compounds are used as chain-stoppers, they can be added in one embodiment to the reaction mixture during the reaction, or, in another embodiment, before the beginning of the reaction between resorcinol moiety and acid chloride moiety. When hydroxy-terminated resorcinol arylate-containing precondensate or oligomers are prepared, then chain-stopper may be absent or only present in small amounts to aid control of oligomer molecular weight.

[0048] In another embodiment the invention may encompass the inclusion of at least one branching agent such as a trifunctional or higher functional carboxylic acid chloride and/or trifunctional or higher functional phenol. Such branching agents, if included, can typically be used in quantities of 0.005 to 1 mole %, based on dicarboxylic acid dichlorides or resorcinol moieties used, respectively. Suitable branching agents include, for example, trifunctional or higher carboxylic acid chlorides, such as trimesic acid trichloride, cyanuric acid trichloride, 3,3′,4,4′-benzophenone tetracarboxylic acid tetrachloride, 1,4,5,8-naphthalene tetracarboxylic acid tetrachloride or pyromellitic acid tetrachloride, and trifunctional or higher phenols, such as phloroglucinol, 4,6-dimethyl-2,4,6-tri-(4-hydroxyphenyl)-2-heptene, 4,6-dimethyl-2,4,6-tri-(4-hydroxyphenyl)-heptane, 1,3,5-tri-(4-hydroxyphenyl)-benzene, 1,1,1-tri-(4-hydroxyphenyl)-ethane, tri-(4-hydroxyphenyl)-phenyl methane, 2,2-bis-[4,4-bis-(4-hydroxyphenyl)-cyclohexyl]-propane, 2,4-bis-(4-hydroxyphenylisopropyl)-phenol, tetra-(4-hydroxyphenyl)-methane, 2,6-bis-(2-hydroxy-5-methylbenzyl)-4-methyl phenol, 2-(4-hydroxyphenyl)-2-(2,4-dihydroxyphenyl)-propane, tetra-(4-[4-hydroxyphenylisopropyl]-phenoxy)-methane, 1,4-bis-[(4,4-dihydroxytriphenyl)methyl]-benzene. Phenolic branching agents may be introduced first with the resorcinol moieties whilst acid chloride branching agents may be introduced together with acid dichlorides.

[0049] For some applications such as for copolymer formation the resorcinol arylate-containing polymer may remain in solution for subsequent process steps. In other instances such as in the production of resorcinol arylate polyester the polymer will normally be isolated from solution. Therefore, in another embodiment of the invention the resorcinol arylate-containing polymer is recovered from the reaction mixture. Recovery methods are well known to those skilled in the art and may include such steps as acidification of the mixture, for example with phosphorous acid; subjecting the mixture to liquid-liquid phase separation; washing the organic phase with water and/or a dilute acid such as hydrochloric acid or phosphoric acid; precipitating by usual methods such as through treatment with water or anti-solvent precipitation with, for example, methanol, ethanol, and/or isopropanol; isolating the resulting precipitates; and drying to remove residual solvents.

[0050] If desired, the resorcinol arylate polymers of the invention may be made by the present method further comprising the addition of a reducing agent. Suitable reducing agents include, for example, sodium sulfite, sodium gluconate, or a borohydride, such as sodium borohydride. When present, any reducing agents are typically used in quantities of from 0.25 to 2 mole %, based on moles of resorcinol moiety.

[0051] In one of its embodiments the invention comprises thermally stable resorcinol arylate polyesters made by the present method and substantially free of anhydride linkages linking at least two mers of the polyester chain. In a particular embodiment said polyesters comprise dicarboxylic acid residues derived from a mixture of iso- and terephthalic acids as illustrated in Formula VII:

[0052] wherein R is at least one of C₁₋₁₂ alkyl or halogen, n is 0-3, and m is at least about 8. In various embodiments n is zero and m is between about 10 and about 300. The molar ratio of isophthalate to terephthalate is in one embodiment about 0.25-4.0:1, in another embodiment about 0.4-2.5:1, and in still another embodiment about 0.67-1.5:1. Substantially free of anhydride linkages means that said polyesters show decrease in molecular weight in one embodiment of less than 30% and in another embodiment of less than 10% upon heating said polymer at a temperature of about 280-290° C. for five minutes.

[0053] The present invention also encompasses thermally stable copolymers containing segments comprising resorcinol arylate polyester chain members made by the present method and substantially free of anhydride linkages linking at least two mers of the copolymer chain. Thus, in another of its embodiments the present invention comprises thermally stable copolyesters comprising resorcinol arylate polyester chain members in combination with dicarboxylic acid or diol alkylene chain members (so-called “soft-block” segments), said copolyesters being substantially free of anhydride linkages in the polyester segments. Substantially free of anhydride linkages means that the copolyesters show decrease in molecular weight in one embodiment of less than 10% and in another embodiment of less than 5% upon heating said copolyester at a temperature of about 280-290° C. for five minutes. Related copolyesters containing soft-block segments are disclosed in commonly owned U.S. Pat. No. 5,916,997.

[0054] The term soft-block as used herein, indicates that some segments of the polymers are made from non-aromatic monomer units. Such non-aromatic monomer units are generally aliphatic and are known to impart flexibility to the soft-block-containing polymers. The copolymers include those comprising structural units of Formulas I, VIII, and IX:

[0055] wherein R and n are as previously defined, Z is a divalent aromatic radical, R² is a C₃₋₂₀ straight chain alkylene, C₃₋₁₀ branched alkylene, or C₄₋₁₀ cyclo- or bicycloalkylene group, and R³ and R⁴ each independently represent

[0056] wherein Formula IX contributes from about 1 to about 45 mole percent to the ester linkages of the polyester. Additional embodiments of the present invention provide a composition wherein Formula IX contributes in various embodiments from about 5 to about 40 mole percent to the ester linkages of the polyester, and in other embodiments from about 5 to about 20 mole percent to the ester linkages of the polyester. Another embodiment provides a composition wherein R² represents in one embodiment C₃₋₁₄ straight chain alkylene, or C₅₋₆ cycloalkylene, and in another embodiment R² represents C₃₋₁₀ straight-chain alkylene or C₆-cycloalkylene. Formula VIII represents an aromatic dicarboxylic acid residue. The divalent aromatic radical Z in Formula VIII may be derived in various embodiments from at least one of the suitable dicarboxylic acid residues as defined hereinabove, and in some embodiments at least one of 1,3-phenylene, 1,4-phenylene, or 2,6-naphthylene. In various embodiments Z comprises at least about 40 mole percent 1,3-phenylene. In various embodiments of copolyesters containing soft-block chain members n in Formula I is zero.

[0057] In various embodiments copolyesters containing resorcinol arylate chain members are those comprising from about 1 to about 45 mole % sebacate or cyclohexane-1,4-dicarboxylate units. In a particular embodiment a copolyester containing resorcinol arylate chain members is one comprising resorcinol isophthalate and resorcinol sebacate units in molar ratio between 8.5:1.5 and 9.5:0.5. In one embodiment said copolyester is prepared using sebacoyl chloride in combination with isophthaloyl dichloride.

[0058] In another of its embodiments the present invention comprises thermally stable block copolyestercarbonates comprising resorcinol arylate-containing block segments in combination with organic carbonate block segments. The segments comprising resorcinol arylate chain members in such copolymers are substantially free of anhydride linkages. Substantially free of anhydride linkages means that the copolyestercarbonates show decrease in molecular weight in one embodiment of less than 10% and in another embodiment of less than 5% upon heating said copolyestercarbonate at a temperature of about 280-290° C. for five minutes. Related block copolyestercarbonates are disclosed in commonly owned, co-pending application Ser. No. 09/416,529, filed Oct. 12, 1999.

[0059] The block copolyestercarbonates include those comprising alternating arylate and organic carbonate blocks, typically as illustrated in Formula X, wherein R and n are as previously defined, and R⁵ is at least one divalent organic radical

[0060] The arylate blocks have a degree of polymerization (DP), represented by m, in one embodiment of at least about 4, in another embodiment of at least about 10, in another embodiment of at least about 20 and in still another embodiment of about 30-150. The DP of the organic carbonate blocks, represented by p, is in one embodiment generally at least about 10, in another embodiment at least about 20 and in still another embodiment about 50-200. The distribution of the blocks may be such as to provide a copolymer having any desired weight proportion of arylate blocks in relation to carbonate blocks. In general, the content of arylate blocks is in one embodiment about 6-95% by weight, in another embodiment about 10-95% by weight, and in another embodiment about 50-95% by weight. In some particular embodiments the content of arylate blocks in the copolymer is about 10-30% by weight, and in other particular embodiments about 75-95% by weight.

[0061] Although a mixture of iso- and terephthalate is illustrated in Formula X, the dicarboxylic acid residues in the arylate blocks may be derived from any suitable dicarboxylic acid residue, as defined hereinabove, or mixture of suitable dicarboxylic acid residues, including those derived from aliphatic diacid dichlorides (so-called “soft-block” segments). In various embodiments n is zero and the arylate blocks comprise dicarboxylic acid residues derived from a mixture of iso- and terephthalic acid residues, wherein the molar ratio of isophthalate to terephthalate is in one embodiment about 0.25-4.0:1, in another embodiment about 0.4-2.5:1, and in still another embodiment about 0.67-1.5:1.

[0062] In the organic carbonate blocks, each R⁵ is independently a divalent organic radical. In various embodiments said radical comprises at least one dihydroxy-substituted aromatic hydrocarbon, and at least about 60 percent of the total number of R⁵ groups in the polymer are aromatic organic radicals and the balance thereof are aliphatic, alicyclic, or aromatic radicals. Suitable R⁵ radicals include m-phenylene, p-phenylene, 4,4′-biphenylene, 4,4′-bi(3,5-dimethyl)-phenylene, 2,2-bis(4-phenylene)propane, 6,6′-(3,3,3′,3′-tetramethyl-1,1′-spirobi[1H-indan]) and similar radicals such as those which correspond to the dihydroxy-substituted aromatic hydrocarbons disclosed by name or formula (generic or specific) in U.S. Pat. No. 4,217,438.

[0063] In some embodiments each R⁵ is an aromatic organic radical and in other embodiments a radical of Formula XI:

—A¹—Y—A²—  Formula XI

[0064] wherein each A¹ and A² is a monocyclic divalent aryl radical and Y is a bridging radical in which one or two carbon atoms separate A¹ and A². The free valence bonds in Formula XI are usually in the meta or para positions of A¹ and A² in relation to Y. Compounds in which R⁵ has Formula XI are bisphenols, and for the sake of brevity the term “bisphenol” is sometimes used herein to designate the dihydroxy-substituted aromatic hydrocarbons. It should be understood, however, that non-bisphenol compounds of this type may also be employed as appropriate.

[0065] In Formula XI, A¹ and A² typically represent unsubstituted phenylene or substituted derivatives thereof, illustrative substituents (one or more) being alkyl, alkenyl, and halogen (particularly bromine). In one embodiment unsubstituted phenylene radicals are preferred. Both A¹ and A² are often p-phenylene, although both may be o- or m-phenylene or one o- or m-phenylene and the other p-phenylene.

[0066] The bridging radical, Y, is one in which one or two atoms, separate A¹ from A². In a particular embodiment one atom separates A¹ from A². Illustrative radicals of this type are —O—, —S—, —SO—or —SO₂—, methylene, cyclohexyl methylene, 2-[2.2.1]-bicycloheptyl methylene, ethylene, isopropylidene, neopentylidene, cyclohexylidene, cyclopentadecylidene, cyclododecylidene, adamantylidene, and like radicals.

[0067] In some embodiments gem-alkylene (commonly known as “alkylidene”) radicals are preferred. Also included, however, are unsaturated radicals. In some embodiments the preferred bisphenol is 2,2-bis(4-hydroxyphenyl)propane (bisphenol-A or BPA), in which Y is isopropylidene and A¹ and A² are each p-phenylene. Depending upon the molar excess of resorcinol moiety present in the reaction mixture, R⁵ in the carbonate blocks may at least partially comprise resorcinol moiety. In other words, in some embodiments of the invention carbonate blocks of Formula X may comprise a resorcinol moiety in combination with at least one other dihydroxy-substituted aromatic hydrocarbon.

[0068] Diblock, triblock, and multiblock copolyestercarbonates are encompassed in the present invention. The chemical linkages between blocks comprising resorcinol arylate chain members and blocks comprising organic carbonate chain members may comprise at least one of

[0069] (a) an ester linkage between a suitable dicarboxylic acid residue of an arylate moiety and an —O—R⁵—O— moiety of an organic carbonate moiety, for example as typically illustrated in Formula XII, wherein R⁵ is as previously defined:

[0070] and (b) a carbonate linkage between a diphenol residue of a resorcinol arylate moiety and a —(C═O)—O— moiety of an organic carbonate moiety as shown in Formula XIII, wherein R and n are as previously defined:

[0071] The presence of a significant proportion of ester linkages of the type (a) may result in undesirable color formation in the copolyestercarbonates. Although the invention is not limited by theory, it is believed that color may arise, for example, when R⁵ in Formula XII is bisphenol A and the moiety of Formula XII undergoes Fries rearrangement during subsequent processing and/or light-exposure. In one embodiment the copolyestercarbonate is substantially comprised of a diblock copolymer with a carbonate linkage between resorcinol arylate block and an organic carbonate block. In another embodiment the copolyestercarbonate is substantially comprised of a triblock carbonate-ester-carbonate copolymer with carbonate linkages between the resorcinol arylate block and organic carbonate end-blocks.

[0072] Copolyestercarbonates with at least one carbonate linkage between a thermally stable resorcinol arylate block and an organic carbonate block are typically prepared from resorcinol arylate-containing oligomers prepared by various embodiments of the invention and containing in one embodiment at least one and in another embodiment at least two hydroxy-terminal sites. Said oligomers typically have weight average molecular weight in one embodiment of about 10,000 to about 40,000, and in another embodiment of about 15,000 to about 30,000. Thermally stable copolyestercarbonates may be prepared by reacting said resorcinol arylate-containing oligomers with phosgene, at least one chain-stopper, and at least one dihydroxy-substituted aromatic hydrocarbon in the presence of a catalyst such as a tertiary amine.

[0073] It is believed that the weatherability and certain other beneficial properties of the polymers comprising resorcinol arylate polyester chain members of the invention are attributable, at least in part, to the occurrence of thermally or photochemically induced Fries rearrangement of arylate blocks to yield o-hydroxybenzophenone moieties or analogs thereof which serve as stabilizers to UV radiation. More particularly, at least a portion of resorcinol arylate polyester chain members can rearrange to yield chain members with at least one hydroxy group ortho to at least one ketone group. Such rearranged chain members are typically o-hydroxybenzophenone-type chain members comprising one or more of the following structural moieties

[0074] wherein R and n are as previously defined. The o-hydroxy-benzophenone-type chain members resulting from rearrangement of resorcinol arylate chain members can be present in resorcinol arylate polyesters and in resorcinol arylate polyester-containing copolymers, including resorcinol arylate-containing copolyestercarbonates and resorcinol arylate-containing copolyesters containing soft-blocks. It is also contemplated to introduce moieties of the types illustrated in Formulas XIV, XV, and XVI via synthesis and polymerization of appropriate monomers in both homopolymers and copolymers by the method of the present invention. In one embodiment the present invention provides thermally stable polyesters, copolyestercarbonates, and copolyesters comprising structural units represented by Formulas III and XIV, wherein the molar ratio of structural units represented by Formula III to structural units represented by Formula XIV ranges in one embodiment from about 99:1 to about 1:1, and in another embodiment from about 99:1 to about 80:20.

[0075] The polymers and copolymers comprising thermally stable resorcinol arylate polyester chain members may also be employed in blends with at least one other polymer, especially polycarbonates (hereinafter sometimes designated “PC”), polyesters, copolyestercarbonates, polyarylates, polyetherimides, polyphenylene ethers, and addition polymers. Related blends are disclosed in commonly owned U.S. Pat. No. 6,143,839.

[0076] The polycarbonates in the blend compositions of the invention are, for the most part, similar in molecular structure to the carbonate blocks of the block copolyestercarbonate as described hereinabove, with bisphenol-A homo- and copolycarbonates generally being preferred in some embodiments. Polyesters are illustrated by poly(alkylene dicarboxylates), especially poly(ethylene terephthalate) (hereinafter sometimes designated “PET”), poly(1,4-butylene terephthalate) (hereinafter sometimes designated “PBT”), poly(trimethylene terephthalate) (hereinafter sometimes designated “PTT”), poly(ethylene naphthalate) (hereinafter sometimes designated “PEN”), poly(butylene naphthalate) (hereinafter sometimes designated “PBN”), poly(cyclohexanedimethanol terephthalate), poly(cyclohexanedimethanol-co-ethylene terephthalate) (hereinafter sometimes designated “PETG”), and poly(1,4-cyclohexanedimethyl-1,4-cyclohexanedicarboxylate) (hereinafter sometimes designated “PCCD”), and especially poly(alkylene arenedioates), with poly(ethylene terephthalate) and poly(1,4-butylene terephthalate) being preferred in some embodiments.

[0077] Copolyestercarbonates may also be used in blends with polymers comprising resorcinol arylate polyester chain members. Such copolymers comprise, in addition to the organic carbonate units, ester units such as isophthalate and/or terephthalate. The copolyestercarbonates which find use in the blends of the instant invention and the methods for their preparation are well known in the art as disclosed in, for example, U.S. Pat. Nos. 3,030,331; 3,169,121; 3,207,814; 4,194,038; 4,156,069; 4,238,596; 4,238,597; 4,487,896; and 4,506,065.

[0078] Polyarylates that may be employed in blends include those known in the art. They often comprise structural units derived from aromatic dihydroxy compounds and aromatic dicarboxylic acid compounds described herein as suitable for preparation of polycarbonates, polyesters, and copolyestercarbonates. In various embodiments polyarylates comprise those with structural units comprising the 1,3-dihydroxybenzene moiety present in the arylate blocks of the copolyestercarbonates, those with structural units comprising any organic dihydroxy compound added in the carbonate block formation step in synthesis of said copolyestercarbonates, and those with structural units comprising both of the aforementioned dihydroxy moieties. Illustrative examples include polyarylates comprising terephthalate and/or isophthalate structural units in combination with one or more of unsubstituted resorcinol, substituted resorcinol, and bisphenol A. The polyetherimide resins useful with the present invention are generically known compounds whose preparation and properties are described in U.S. Pat. Nos. 3,803,085 and 3,905,942.

[0079] Suitable addition polymers include homopolymers and copolymers, especially homopolymers of alkenylaromatic compounds, such as polystyrene, including syndiotactic polystyrene, and copolymers of alkenylaromatic compounds with ethylenically unsaturated nitriles, such as acrylonitrile and methacrylonitrile; dienes, such as butadiene and isoprene; and/or acrylic monomers, such as ethyl acrylate. These latter copolymers include the ABS (acrylonitrile-butadiene-styrene) and ASA (acrylonitrile-styrene-alkyl acrylate) copolymers.

[0080] In another embodiment the invention encompasses blends of polymers and/or copolymers comprising thermally stable resorcinol arylate polyester chain members with at least two other polymers. Said at least two other polymers may comprise miscible, immiscible, and compatibilized blends including, but not limited to, PC/ABS, PC/ASA, PC/PBT, PC/PET, PC/polyetherimide, polyester/polyetherimide, polyphenylene ether/polystyrene, polyphenylene ether/polyamide, and polyphenylene ether/polyester.

[0081] The blend compositions of the invention may be prepared by such conventional operations as solvent blending and melt blending. In some embodiments blend preparation is by melt blending, illustrative examples of which include extrusion. The blends may additionally contain art-recognized additives including, but not limited to, pigments, dyes, impact modifiers, UV screeners, UV absorbers, flame retardants, fillers, stabilizers, heat stabilizers, color stabilizers, flow aids, ester interchange inhibitors, and mold release agents. It is intended that the blend compositions include simple physical blends and any reaction products thereof, as illustrated, for example, by polyester-polycarbonate transesterification products.

[0082] Proportions of the polymers comprising resorcinol arylate polyester chain members in such blends are determined chiefly by the resulting proportions of arylate blocks, which most often comprise the active weatherability-improving entities, typical proportions providing about 10-50% by weight of arylate blocks in the blend. In blends where some degree of incompatibility may exist between the polymers comprising resorcinol arylate polyester chain members of the invention and the polycarbonates, polyesters, or addition polymers with which they may be combined, said blends are sometimes not fully transparent. However, transparent blends may often be prepared, if desired, by adjusting the length of the arylate blocks in the polymers comprising resorcinol arylate polyester chain members. The other properties of said blends are generally excellent.

[0083] Compositions comprising resorcinol arylate polyester chain members made by various embodiments of the method of the invention typically have significantly lower color, both before and after thermal processing, than related compositions made by melt methods, interfacial methods, and solution methods of the prior art. In particular, melt methods typically provide resorcinol arylate polyester with tan to dark brown color while the present interfacial method provides very lightly colored or essentially colorless polyester. The present compositions may be used in various applications, especially those involving outdoor use and storage, and hence requiring resistance to weathering. Their light transmitting properties are often similar to those of polycarbonates. Thus, they are often substantially transparent and colorless, and may often be employed as substitutes for polycarbonates in the fabrication of transparent sheet material when improved weatherability is mandated.

[0084] In another embodiment the present invention comprises multilayer articles comprising a substrate layer comprising at least one thermoplastic polymer, thermoset polymer, cellulosic material, glass, ceramic, or metal, and at least one coating layer thereon, said coating layer comprising at least one auxiliary stabilizer additive and at least one polymer comprising structural units derived from at least one 1,3-dihydroxybenzene moiety and at least one aromatic dicarboxylic acid moiety and prepared by methods embodied in the present invention. In the present context a multilayer article is one containing at least two layers. In various embodiments a coating layer comprises at least one thermally stable polymer comprising resorcinol arylate polyester chain members substantially free of anhydride linkages linking at least two mers of the polymer chain. Optionally, the multilayer articles may further comprise an interlayer, for example an adhesive interlayer, between any substrate layer and any thermally stable polymer coating layer. Multilayer articles of the invention include, but are not limited to, those which comprise a substrate layer and a coating layer of said thermally stable polymer; those which comprise a substrate layer with a coating layer of said thermally stable polymer on each side of said substrate layer; and those which comprise a substrate layer and at least one coating layer of said thermally stable polymer with at least one interlayer between a substrate layer and a coating layer. Any interlayer may be transparent, translucent, or opaque, and/or may contain an additive, for example a colorant or decorative material such as metal flake. If desired, an overlayer may be included over the coating layer of thermally stable polymer, for example to provide abrasion or scratch resistance. The substrate layer, coating layer of thermally stable polymer, and any interlayers or overcoating layers are often in contiguous superposed contact with one another.

[0085] Within the context of the present invention it should be understood that any coating layer comprising a thermally stable polymer comprising resorcinol arylate polyester chain members may also include polymer comprising o-hydroxy-benzophenone or analogous chain members resulting from Fries rearrangement of said resorcinol arylate chain members, for example after exposure of said coating layer to UV-light. Typically, a preponderance of any polymer comprising o-hydroxy-benzophenone or analogous chain members will be on that side or sides of said coating layer exposed to UV-light and will overlay in a contiguous superposed layer or layers that polymer comprising unrearranged resorcinol arylate chain members. If it is worn away or otherwise removed, polymer comprising o-hydroxybenzophenone or analogous chain members is capable of regenerating or renewing itself from the resorcinol arylate-containing layer or layers, thus providing continuous protection for any UV-light sensitive layers.

[0086] It has been unexpectedly discovered that the presence of at least one auxiliary stabilizer additive in a coating layer comprising a polymer comprising resorcinol arylate polyester chain members may have a beneficial effect on color and other properties despite the fact that polymers comprising resorcinol arylate polyester chain members and their Fries rearrangement products themselves protect against photoyellowing. In one embodiment an auxiliary stabilizer additive is at least one color stabilizer additive. In another embodiment a stabilizer additive is any additive which provides one or both of lower initial color or additional resistance to weathering, as measured for example by initial yellowness index (YI), or by resistance to yellowing and change in color, when compared to a similar coating without at least one stabilizer additive. In another embodiment a stabilizer additive is any additive which provides improved retention of molecular weight and/or melt viscosity after thermal processing of a coating layer, when compared to a similar coating without at least one stabilizer additive. In another particular embodiment the stabilizer additive comprises at least one auxiliary light stabilizer additive, such as a UV absorber. In one embodiment the presence of at least one auxiliary UV absorber as stabilizer additive provides additional resistance to weathering, for example as measured by initial yellowness index (YI), or resistance to yellowing and change in color, when compared to a similar coating without at least one auxiliary UV absorber. Since resorcinol arylate-comprising polymers generate UV absorber in situ, it is unexpected that the addition of auxiliary stabilizer additive such as a UV absorber would affect the amount of color or yellowness generated.

[0087] In various embodiments the unexpected beneficial effect of at least one stabilizer additive in a polymer composition comprising resorcinol arylate polyester chain members is not limited to said polymer made by any particular method of preparation. Thus, the unexpected beneficial effect of at least one stabilizer additive may be realized in one embodiment in a coating layer composition comprising a polymer comprising resorcinol arylate polyester chain members; in another embodiment in a coating layer composition comprising a polymer consisting essentially of resorcinol arylate polyester chain members; in another embodiment in a coating layer composition comprising a copolymer comprising resorcinol arylate polyester chain members in combination with C₃₋₂₀ straight chain alkylene, C₃₋₁₀ branched alkylene, or C₄₋₁₀ cyclo- or bicyclo-alkylene chain members; and in still another embodiment in a coating layer composition comprising a polymer comprising resorcinol arylate polyester chain members in combination with organic carbonate segments. Said polymer comprising resorcinol arylate polyester chain members may be made using any known method including, but not limited to, those methods disclosed in U.S. Pat. Nos. 5,916,997 and 6,369,170; and in application Ser. No. 09/368,705, filed Aug. 5, 1999; application Ser. No. 09/416,529, filed Oct. 12, 1999; application Ser. No. 09/916,160, filed Jul. 26, 2001; application Ser. No. 10/000,913; filed Nov. 2, 2001; application Ser. No. 10/105,563, filed Mar. 25, 2002; application Ser. No. 10/105,565, filed Mar. 25, 2002; and application Ser. No. (RD-29522), filed December, 2002. In a particular embodiment the unexpected beneficial effect of at least one stabilizer additive may be realized in a coating layer composition comprising a polymer comprising resorcinol arylate polyester chain members, said polymer being made by an interfacial method comprising the steps of: (a) combining at least one resorcinol moiety and at least one catalyst in a mixture of water and at least one organic solvent substantially immiscible with water; and (b) adding to the mixture from (a) at least one dicarboxylic acid dichloride while maintaining the pH between 3 and 8.5 through the presence of an acid acceptor, wherein the total molar amount of acid chloride groups is stoichiometrically deficient relative to the total molar amount of phenolic groups.

[0088] In various embodiments the unexpected beneficial effect of at least one stabilizer additive in a polymer composition comprising resorcinol arylate polyester chain members is not limited to a coating layer comprising said polymer composition. Said benefit may also be obtained in a polymer composition comprising resorcinol arylate polyester chain members when said composition is a part of a multilayer article other than or in addition to a coating layer, and when said composition comprises a unitary article rather than a layered article.

[0089] In various embodiments auxiliary stabilizer additives include those known in the art which stabilize or improve a physical or optical property of a polyester or polycarbonate or polyestercarbonate compared to that property in the absence of said stabilizer. For example, illustrative UV absorbers include, but are not limited to, hydroxybenzophenones, hydroxybenzotriazoles, hydroxybenzotriazines, cyanoacrylates, oxanilides, and benzoxazinones. In some particular embodiments illustrative UV absorbers include, but are not limited to, 2-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)-phenol (sometimes known as CYASORB 5411); 2-hydroxy-4-n-octyloxybenzophenone (sometimes known as CYASORB 531); 2-[4,6-bis(2,4-dimethylphenyl)-1,3,5-triazin-2-yl]-5-(octyloxy)-phenol (sometimes known as CYASORB 1164); 2,2′-(1,4-phenylene)bis(4H-3,1-benzoxazin-4-one) (sometimes known as CYASORB UV-3638); and 1,3-bis[(2-cyano-3,3-diphenylacryloyl)oxy]-2,2-bis[[(2-cyano-3,3-diphenylacryloyl)oxy]methyl]propane (sometimes known as UVINUL 3030). In other particular embodiments UV absorbers are 2,2′-(1,4-phenylene)bis(4H-3,1-benzoxazin-4-one) or 1,3-bis[(2-cyano-3,3-diphenylacryloyl)oxy]-2,2-bis[[(2-cyano-3,3-diphenylacryloyl)oxy]methyl]propane. Illustrative UV absorbers also include nano-size inorganic materials such as titanium oxide, cerium oxide, and zinc oxide, all with particle size less than about 100 nanometers. Illustrative examples of stabilizer additives also include carbodiimides, such as bis-(2,6-diisopropylphenyl)carbodiimide and polycarbodiimides; hindered amine light stabilizers; hindered phenols; phosphites and phosphorous acid.

[0090] Illustrative examples of stabilizer additives also include moieties having more than one epoxy functionality therein. In some embodiments illustrative examples stabilizer additives include moieties having two epoxy functionalities therein. In other embodiments moieties having more than one epoxy functionality therein have two terminal epoxy functionalities. In other embodiments moieties having more than one epoxy functionality therein contain only carbon, hydrogen and oxygen, and have a molecular weight of below about 1000 to facilitate blending in the composition. Examples of suitable epoxy compounds include, but are not limited to, 3,4-epoxycyclohexylmethyl-3′,4′-epoxycyclohexanecarboxylate, bis(3,4-epoxycyclohexylmethyl) adipate, vinylcyclohexene di-epoxide, bisphenol diglycidyl ethers, diglycidyl adducts of amines and amides, diglycidyl adducts of carboxylic acids and the like. Particular epoxy compounds suitable for use in this invention include, but are not limited to, 3,4-epoxy-6-methylcyclohexylmethyl-3′,4′-epoxy-6′-methylcyclohexane carboxylate, 2,3-epoxy-cylcohexylmethyl-3′,4′-epoxy cyclohexane carboxylate, 4-(3,4-epoxy-5-methylcyclohexyl) butyl-3′,4′-epoxy cyclohexane carboxylate, 3,4-epoxy cyclohexyl ethylene oxide, bisphenol-A diglycidyl ether, tetrabromobisphenol-A diglycidyl ether, diglycidyl ester of phthalic acid, diglycidyl ester of hexahydrophthalic acid, epoxidized soybean oil, epoxidized linseed oil, bis-epoxycyclohexyl adipate, butadiene diepoxide, and epoxidized polybutadiene. In one particular embodiment a suitable epoxy compound is 3,4-epoxycyclohexylmethyl-3′,4′-epoxycyclohexanecarboxylate commercially available as ERL-4221 epoxy from Union Carbide.

[0091] Other suitable stabilizer additives are known in the art and are disclosed in standard reference works, an illustrative example of which is “Plastics Additives Handbook”, 5th edition, edited by H. Zweifel, Hanser Publishers. In some embodiments mixtures of stabilizer additives are particularly effective, especially mixtures of the abovementioned stabilizer additives.

[0092] The amount of any stabilizer additive employed is in one embodiment in a range between about 0.0005 wt. % and 10 wt. %, in another embodiment in a range between about 0.001 wt. % and about 10 wt. %, in another embodiment in a range between about 0.005 wt. % and about 8 wt. %, in another embodiment in a range between about 0.03 wt. % and about 8 wt. %, in another embodiment in a range between about 0.1 wt. % and about 6 wt. %, in another embodiment in a range between about 0.2 wt. % and about 5 wt. %, in another embodiment in a range between about 0.5 wt. % and about 5 wt. %, in still another embodiment in a range between about 1 wt. % and about 5 wt. %, and in still another embodiment in a range between about 1 wt. % and about 3 wt. %, based on the combined weights of stabilizer and polymer comprising resorcinol arylate polyester chain members in a coating layer. When at least one epoxide is employed as stabilizer additive, it may be employed in any effective amount, and in particular embodiments in amounts in those ranges given for additives hereinabove. In some other particular embodiments at least one epoxide stabilizer additive may be employed in a range of between about 0.01 wt. % and about 5 wt. %; in other particular embodiments in a range of between about 0.02 wt. % and about 5 wt. %; in other particular embodiments in a range of between about 0.02 wt. % and about 3 wt. %; and in other particular embodiments in a range of between about 0.02 wt. % and about 2 wt. %; all percentages being based on the combined weights of organic difunctional epoxide and polymer comprising resorcinol arylate polyester chain members in a coating layer.

[0093] When at least one epoxide is employed as stabilizer additive, then at least one catalyst compound may optionally be present in the composition in some embodiments of the invention. Suitable catalysts comprise salts free from direct carbon-phosphorus bonds and containing at least one of alkali metal cations and alkaline earth metal cations and halide anions. It is apparent that this class contains a large number of compounds. They comprise alkali metal halides, alkali metal carboxylates, alkali metal enolates, amine hydrohalides, alkali metal carbonates and quaternary ammonium halides. Illustrative compounds within this class include, but are not limited to, lithium fluoride, lithium iodide, potassium bromide, potassium iodide, sodium dihydrogen phosphate, sodium acetate, sodium benzoate, sodium caproate, sodium stearate, sodium ascorbate, magnesium caproate and dodecyltrimethylammonium bromide. Salts of aliphatic carboxylic acids containing at least about 18 carbon atoms, especially the alkali metal stearates and preferably sodium stearate, have certain advantages over the other catalysts employed according to the invention and are therefore often preferred. In the first place, their use permits extrusion of the polyester-difunctional epoxide composition at substantially higher feed rates than those which are effective in their absence. In the second place, they may suppress the formation of acrolein, a by-product from glycidyl reagents. In the third place, they may impart substantially less odor to the composition than certain other compounds useful as catalysts, especially amines.

[0094] The catalyst component can be present in the composition of the present invention in any effective amount. In some embodiments the catalyst is present in an amount ranging from about 0.01 to about 1 weight percent, and in other embodiments in an amount ranging from about 0.03 to about 0.1 weight percent; all percentages being based on the combined weights of organic difunctional epoxide and polymer, comprising resorcinol arylate polyester chain members in a coating layer.

[0095] A stabilizer additive may be combined with coating layer using known methods. In one embodiment stabilizer additive is at least partially dissolved in a solution with components of a coating layer, and a film of coating layer comprising stabilizer additive is solvent cast. In another embodiment stabilizer additive is at least partially dissolved in a solution and impregnated from said solution into solid or at least partially solid coating layer. In still another embodiment stabilizer additive is combined with coating layer in a melt method such as co-extrusion. If desired, the stabilizer additive may be combined with coating layer in the form of a solution of stabilizer additive, for example in water or organic solvent. In one embodiment an aqueous solution of phosphorous acid is employed as stabilizer additive.

[0096] The multilayer articles typically have outstanding initial gloss, improved initial color, weatherability, impact strength, and resistance to organic solvents encountered in their final applications. Said articles may also be recyclable by reason of the compatibility of the discrete layers therein.

[0097] The material of the substrate layer in the articles of this invention may be at least one thermoplastic polymer, whether addition or condensation prepared. Thermoplastic polymers include, but are not limited to, polycarbonates, particularly aromatic polycarbonates, polyacetals, polyarylene ethers, polyphenylene ethers, polyarylene sulfides, polyphenylene sulfides, polyimides, polyamideimides, polyetherimides, polyetherketones, polyaryletherketones, polyetheretherketones, polyetherketoneketones, polyamides, polyesters, liquid crystalline polyesters, polyetheresters, polyetheramides, polyesteramides, and polyestercarbonates (other than those employed for the coating layer, as defined hereinafter). In some embodiments polycarbonates and polyesters are preferred. A substrate layer may additionally contain art-recognized additives including, but not limited to, colorants, pigments, dyes, impact modifiers, stabilizers, color stabilizers, heat stabilizers, UV screeners, UV absorbers, flame retardants, fillers, flow aids, ester interchange inhibitors, and mold release agents.

[0098] Suitable polycarbonates include homopolycarbonates comprising structural units of the type described for the organic carbonate blocks in the copolyestercarbonates of the invention. In some embodiments the polycarbonates are bisphenol A homo- and copolycarbonates. In various embodiments the weight average molecular weight of the initial polycarbonate ranges from about 5,000 to about 100,000; in other embodiments the weight average molecular weight of the initial polycarbonate ranges from about 25,000 to about 65,000.

[0099] The polycarbonate substrate may also be a copolyestercarbonate (other than that copolyestercarbonate employed for the coating layer as defined hereinafter). Such copolymers typically comprise, in addition to the organic carbonate units, ester units such as isophthalate and/or terephthalate. The copolyestercarbonates which find use as substrates in the instant invention and the methods for their preparation are well known in the art as disclosed in, for example, U.S. Pat. Nos. 3,030,331; 3,169,121; 3,207,814; 4,194,038; 4,156,069; 4,238,596; 4,238,597; 4,487,896; and 4,506,065.

[0100] Polyester substrates include, but are not limited to, poly(alkylene dicarboxylates), especially poly(ethylene terephthalate), poly(1,4-butylene terephthalate), poly(trimethylene terephthalate), poly(ethylene naphthalate), poly(butylene naphthalate), poly(cyclohexanedimethanol terephthalate), poly(cyclohexanedimethanol-co-ethylene terephthalate), and poly(1,4-cyclohexanedimethyl-1,4-cyclohexanedicarboxylate). Also included are polyarylates as described hereinabove, illustrative examples of which include those comprising structural units derived from bisphenol A, terephthalic acid, and isophthalic acid.

[0101] Suitable addition polymer substrates include homo- and copolymeric aliphatic olefin and functionalized olefin polymers (which are homopolymers and copolymers comprising structural units derived from aliphatic olefins or functionalized olefins or both), and their alloys or blends. Illustrative examples include, but are not limited to, polyethylene, polypropylene, thermoplastic polyolefin (“TPO”), ethylene-propylene copolymer, poly(vinyl chloride), poly(vinyl chloride-co-vinylidene chloride), poly(vinyl fluoride), poly(vinylidene fluoride), polyvinyl acetate), poly(vinyl alcohol), poly(vinyl butyral), poly(acrylonitrile), acrylic polymers such as those of (meth)acrylamides or of alkyl (meth)acrylates such as poly(methyl methacrylate) (“PMMA”), and polymers of alkenylaromatic compounds such as polystyrenes, including syndiotactic polystyrene. In some embodiments the preferred addition polymers are polystyrenes and especially the so-called ABS and ASA copolymers, which may contain thermoplastic, non-elastomeric styrene-acrylonitrile side chains grafted on an elastomeric base polymer of butadiene and alkyl acrylate, respectively.

[0102] Blends of any of the foregoing polymers may also be employed as substrates. Typical blends include, but are not limited to, those comprising PC/ABS, PC/ASA, PC/PBT, PC/PET, PC/polyetherimide, PC/polysulfone, polyester/polyetherimide, PMMA/acrylic rubber, polyphenylene ether-polystyrene, polyphenylene ether-polyamide or polyphenylene ether-polyester. Although the substrate layer may incorporate other thermoplastic polymers, the above-described polycarbonates and/or addition polymers often constitute the major proportion thereof.

[0103] The substrate layer in the multilayer articles of this invention may also comprise at least one of any thermoset polymer. Suitable thermoset polymer substrates include, but are not limited to, those derived from epoxys, cyanate esters, unsaturated polyesters, diallylphthalate, acrylics, alkyds, phenol-formaldehyde, novolacs, resoles, bismaleimides, PMR resins, melamine-formaldehyde, urea-formaldehyde, benzocyclobutanes, hydroxymethylfurans, and isocyanates. In one embodiment of the invention the thermoset polymer substrate comprises a RIM material. In another embodiment of the invention the thermoset polymer substrate further comprises at least one thermoplastic polymer, such as, but not limited to, polyphenylene ether, polyphenylene sulfide, polysulfone, polyetherimide, or polyester. Said thermoplastic polymer is typically combined with thermoset monomer mixture before curing of said thermoset.

[0104] In one embodiment of the invention a thermoplastic or thermoset substrate layer also incorporates at least one filler and/or pigment. Illustrative extending and reinforcing fillers, and pigments include silicates, zeolites, titanium dioxide, stone powder, glass fibers or spheres, carbon fibers, carbon black, graphite, calcium carbonate, talc, mica, lithopone, zinc oxide, zirconium silicate, iron oxides, diatomaceous earth, calcium carbonate, magnesium oxide, chromic oxide, zirconium oxide, aluminum oxide, crushed quartz, calcined clay, talc, kaolin, asbestos, cellulose, wood flour, cork, cotton and synthetic textile fibers, especially reinforcing fillers such as glass fibers, carbon fibers, and metal fibers, as well as colorants such as metal flakes, glass flakes and beads, ceramic particles, other polymer particles, dyes and pigments which may be organic, inorganic or organometallic. In another embodiment the invention encompasses multilayer articles comprising a filled thermoset substrate layer such as a sheet-molding compound (SMC).

[0105] The substrate layer may also comprise at least one cellulosic material including, but not limited to, wood, paper, cardboard, fiber board, particle board, plywood, construction paper, Kraft paper, cellulose nitrate, cellulose acetate butyrate, and like cellulosic-containing materials. The invention also encompasses blends of at least one cellulosic material and either at least one thermoset polymer (particularly an adhesive thermoset polymer), or at least one thermoplastic polymer (particularly a recycled thermoplastic polymer, such as PET or polycarbonate), or a mixture of at least one thermoset polymer and at least one thermoplastic polymer.

[0106] Multilayer articles encompassed by the invention also include those comprising at least one glass layer. Typically any glass layer is a substrate layer, although multilayer articles comprising a thermally stable polymer coating layer interposed between a glass layer and a substrate layer are also contemplated. Depending upon the nature of coating and glass layers, at least one adhesive interlayer may be beneficially employed between any glass layer and any thermally stable polymer coating layer. The adhesive interlayer may be transparent, opaque or translucent. For many applications it is preferred that the interlayer be optically transparent in nature and generally have a transmission of greater than about 60% and a haze value less than about 3% with no objectionable color.

[0107] Metal articles exposed to UV-light may exhibit tarnishing and other detrimental phenomena. In another embodiment the invention encompasses multilayer articles comprising at least one metal layer as substrate layer. Representative metal substrates include those comprising brass, aluminum, magnesium, chrome, iron, steel, copper, and other metals or alloys or articles containing them, which may require protection from UV-light or other weather phenomena. Depending upon the nature of coating and metal layers, at least one adhesive interlayer may be beneficially employed between any metal layer and any thermally stable polymer coating layer.

[0108] Also present in the articles of the invention is at least one coating layer comprising at least one polymer comprising structural units derived from at least one 1,3-dihydroxybenzene moiety and at least one aromatic dicarboxylic acid moiety prepared by methods embodied in the present invention. In various embodiments, suitable coating layers comprise polymers comprising thermally stable resorcinol arylate polyester chain members. In other embodiments suitable coating layers comprise resorcinol arylate polyesters, copolyesters (particularly those containing soft-blocks), copolyestercarbonates, and mixtures thereof. Copolyestercarbonates, when used in both substrate layer and in coating layer, are different from each other in molecular structure. More specifically, when the coating layer contains copolyestercarbonate with resorcinol arylate polyester blocks, then any ester blocks in the substrate copolyestercarbonate layer will typically be derived from the same divalent organic radical as contained in the carbonate blocks.

[0109] It is also within the scope of the invention for other polymers to be present which are miscible in at least some proportions with a polymer coating layer comprising at least one thermally stable polymer comprising structural units derived from at least one 1,3-dihydroxybenzene moiety and at least one aromatic dicarboxylic acid moiety. Illustrative examples of at least partially miscible polymers include polyetherimide and polyesters such as PBT, PET, PTT, PEN, PBN, PETG, PCCD, and bisphenol A polyarylate. In one embodiment the coating layer polymer consists essentially of thermally stable resorcinol arylate polyesters, copolyesters, or copolyestercarbonates.

[0110] Another aspect of the invention is a method for preparing a multilayer article which comprises applying at least one thermally stable coating layer to a second layer, said second layer comprising at least one thermoplastic polymer, thermoset polymer, cellulosic material, glass, or metal, and said coating layer comprising at least one polymer comprising structural units derived from at least one 1,3-dihydroxybenzene moiety and at least one aromatic dicarboxylic acid moiety, the polymer being substantially free of anhydride linkages linking at least two mers of the polymer chain.

[0111] In one embodiment of the invention, at least one thermally stable coating layer is applied to a second layer, which may be the substrate layer or at least one intermediate layer ultimately to be disposed between the coating and substrate layers. An intermediate layer may comprise any of the materials suitable for use as the substrate or coating layer, and may further contain fillers and colorants such as described hereinabove. When necessary, it may be specifically chosen so as to provide good adhesion between substrate and coating layers. Colorants of the previously described types may also be present in the coating layer.

[0112] In one embodiment application of the at least one coating layer may be performed by solvent-casting. In another embodiment application of said coating layer comprises fabrication of a separate sheet thereof followed by application to the second layer, or by simultaneous production of both layers, typically in a melt process. Thus, there may be employed such methods as thermoforming, compression molding, co-injection molding, coextrusion, overmolding, blow molding, multi-shot injection molding and placement of a film of the coating layer material on the surface of the second layer followed by adhesion of the two layers, typically in an injection molding apparatus; e.g., in-mold decoration, or in a hot-press. These operations may be conducted under art-recognized conditions.

[0113] It is also within the scope of the invention to apply a structure comprising the coating layer and the second layer to a third, substrate layer, which may be, for example, of a thermoplastic, thermoset, or cellulosic material similar or identical to that of the second layer but different from that of the coating layer. This may be achieved, for example, by charging an injection mold with the structure comprising the coating layer and the second layer and injecting the substrate sheet material behind it. By this method, in-mold decoration and the like are possible. Both sides of the substrate layer may receive the other layers, though in some embodiments it may be preferred to apply them to only one side.

[0114] The thicknesses of the various layers in multilayer articles of this invention are most often as follows:

[0115] substrate—at least about 125μ (microns), or at least about 250μ, or at least about 400μ,

[0116] coating—about 2-2,500, or about 10-250, or about 50-175μ,

[0117] second material, if any—about 2-2,500, or about 10-250, or about 50-175μ,

[0118] total—at least about 125μ, or at least about 250μ, or at least about 400μ.

[0119] The articles of this invention are typically characterized by the usual beneficial properties of the substrate layer, in addition to weatherability as may be evidenced by such properties as improved initial gloss, improved initial color, improved resistance to ultraviolet radiation and maintenance of gloss, improved impact strength, and resistance to organic solvents encountered in their final applications. Depending upon such factors as the coating layer/substrate combination, the multilayer articles may possess recycling capability, which makes it possible to employ the regrind material as a substrate for further production of articles of the invention.

[0120] Multilayer articles which can be made which comprise thermally stable polymers comprising resorcinol arylate polyester chain members include aircraft, automotive, truck, military vehicle (including automotive, aircraft, and water-borne vehicles), scooter, and motorcycle exterior and interior components, including panels, quarter panels, rocker panels, trim, fenders, doors, decklids, trunklids, hoods, bonnets, roofs, bumpers, fascia, grilles, mirror housings, pillar appliques, cladding, body side moldings, wheel covers, hubcaps, door handles, spoilers, window frames, headlamp bezels, headlamps, tail lamps, tail lamp housings, tail lamp bezels, license plate enclosures, roof racks, and running boards; enclosures, housings, panels, parts, and trim for outdoor vehicles and devices; enclosures for electrical and telecommunication devices; outdoor furniture; aircraft components; boats and marine equipment, including trim, enclosures, and housings; outboard motor housings; depth finder housings, personal water-craft; jet-skis; pools; spas; hot-tubs; steps; step coverings; building and construction applications such as glazing, roofs, countertops, windows, window trim, floors, decorative window furnishings or treatments; treated glass covers for pictures, paintings, posters, and like display items; optical lenses; ophthalmic lenses; corrective ophthalmic lenses; implantable ophthalmic lenses; refractors; sheaths for fluorescent tubes; sleeve guards; wall panels, doors and door trim; counter tops; protected graphics; outdoor and indoor signs; enclosures, housings, panels, and parts for automatic teller machines (ATM); enclosures, housings, panels, and parts for lawn and garden tractors, lawn mowers, and tools, including lawn and garden tools; window and door trim; sports equipment and toys; enclosures, housings, panels, and parts for snowmobiles; recreational vehicle panels and components; playground equipment; shoe laces; articles made from plastic-wood combinations; golf course markers; utility pit covers; computer housings; desk-top computer housings; portable computer housings; lap-top computer housings; palm-held computer housings; monitor housings; printer housings; keyboards; FAX machine housings; copier housings; telephone housings; phone bezels; mobile phone housings; radio sender housings; radio receiver housings; light fixtures; lighting appliances; network interface device housings; transformer housings; air conditioner housings; cladding or seating for public transportation; cladding or seating for trains, subways, or buses; meter housings; antenna housings; cladding for satellite dishes; coated helmets and personal protective equipment; coated synthetic or natural textiles; coated photographic film and photographic prints; coated painted articles; coated dyed articles; coated fluorescent articles; coated foam articles; and like applications. The invention further contemplates additional fabrication operations on said articles, such as, but not limited to, molding, in-mold decoration, baking in a paint oven, lamination, and/or thermoforming.

[0121] The invention is illustrated by the following, non-limiting examples. All parts are by weight unless otherwise designated. Molecular weight values for polymeric samples were determined by gel permeation chromatography (GPC) using 3% isopropanol/chloroform eluent at 0.75 milliliters (ml) per minute (min) on a Polymer Labs Mixed C size exclusion column held at 35° C., and calibrated using polystyrene standards, and analyzed with Turbogel software.

EXAMPLE 1

[0122] This example illustrates the preparation of a thermally stable resorcinol arylate polyester with both iso- and terephthalate units. To a one liter, five neck, Morton flask blanketed with nitrogen and equipped with a mechanical stirrer, pH electrode, reflux condenser, two pressure equalizing addition funnels, was charged resorcinol (21.8 grams [g]; 0.198 moles [mol]), resorcinol monobenzoate capping agent (1.07 g; 2.5 mole %), triethylamine (0.274 ml; 1 mole %), dichloromethane (150 ml), and water (100 ml). One addition funnel was charged with sodium hydroxide pellets (16.84 g; 0.42 mol) and water (32 ml), while a solution of isophthaloyl dichloride (20.3 g; 0.1 mol), terephthaloyl dichloride (20.3 g; 0.1 mol), and dichloromethane (150 ml) was added to the second. The pH of the reaction mixture was adjusted to 7.5 with sodium hydroxide prior to the addition of acid chloride solutions, which were added over 6 minutes. The pH of the reaction was maintained between 7.25 and 7.75 for the first ten minutes of reaction. At 11 minutes the reaction the pH was raised to about 10 with the addition of sodium hydroxide and held for an additional 10 minutes. The stirring was stopped and the aqueous layer was removed. The resulting gray organic layer was washed with 1N hydrochloric acid, 0.1N hydrochloric acid, water (three times), and the polymer isolated by precipitation into boiling water yielding a white, fibrous material which was dried in vacuum at 110° C. overnight. The isolated polymer was the desired resorcinol arylate polyester.

Control Example 1

[0123] A polyester of resorcinol with a mixture of iso- and terephthalate was prepared in a blender according to the interfacial method of U.S. Pat. No. 3,460,961. The isolated polymer had weight average molecular weight of about, 289,000. The procedure was modified by addition of 4 mole % chain-stopper (phenol), resulting in polymer with weight average molecular weight of about 51,000.

Control Example 2

[0124] A polyester of resorcinol with a mixture of iso- and terephthalate was prepared according to the solution method of Cohen et al., Journal of Polymer Science: Part A-1, vol. 9, 3263-3299 (1971). To a one-liter, three neck, round bottomed flask equipped with a mechanical stiffer and an addition funnel were charged isophthaloyl dichloride (5.076 g, 25 millimoles [mmol]), terephthaloyl dichloride (5.076 g, 25 mmol), resorcinol (5.506 g, 50 mmol), and tetrahydrofuran (200 ml) dried by distillation from sodium and benzophenone. Polymerization was initiated by dropwise addition of a stoichiometric amount of triethylamine (10.12 g, 10 mmol) over 30 minutes. The mixture then was stirred for 3 hours at room temperature. Triethylamine hydrochloride was removed from the reaction mixture by filtration. The filtrate was slowly poured into methanol (500 ml) in a blender. The precipitated polymer was washed with hot water and dried in a vacuum oven. The isolated polymer had weight average molecular weight of about 47,000.

EXAMPLES 2-11

[0125] These examples illustrate the preparation of hydroxy-terminated resorcinol iso/terephthalate oligomers. Into a 1 liter Morton flask equipped with a mechanical stirrer, pH electrode, condenser, and two addition tubes connected to metering pumps were charged resorcinol (12.11 g, 0.11 mol), water (18 ml), methylene chloride (200 ml), and triethylamine (140 to 560 microliters, 1 to 4 mol % based on acid chlorides). The mixture was stirred at 500 rpm. A two-step addition profile was used for the delivery of acid chloride solution and base solution. In the first step, a majority of base (60 to 80% out of total base amount of 17.5 ml of 33% aqueous sodium hydroxide solution) and the whole acid chloride solution (70 ml solution of isophthaloyl dichloride (10.15 g, 0.05 mol) and terephthaloyl dichloride (10.15 g, 0.05 mol) in methylene chloride) were added at constant rates, and the remaining base was added in the second step at continuously decreasing rate. The base was pumped from graduated burettes and the amount was checked every 30 seconds in order to control the stoichiometry. The pH varied between about 3.5 and about 8. The length of the first step was varied from 7 to 13 minutes with the total step 1 and step 2 time constant at 25 minutes. The reaction mixture was further stirred for 30 minute total reaction time. The reaction conditions and weight average molecular weights of the isolated polymers are shown in Table 1. TABLE 1 % Base Added in 1st Base Addition mol % Oligomer Example Step time (min.) triethylamine Mw^(a) 2 60 7 1 27.3 3 60 7 4 26.9 4 60 13 4 24.5 5 60 13 1 26 6 70 10 2.5 28.3 7 70 10 2.5 23 8 80 7 4 28.4 9 80 7 1 30.8 10 80 13 4 29.5 11 80 13 1 30.4

[0126] A sample of each polymer was analyzed for anhydride content by treatment in solution with diisobutylamine. Polymers prepared using 4 mol % triethylamine showed greater than 95% retention of weight average molecular weight.

EXAMPLES 12-28

[0127] The procedure of Examples 2-11 was repeated except that in some experiments 13 to 15 mol % total excess of resorcinol was used. In some experiments a small amount of capping agent (1 mol % phenol) was added. In some cases; the reaction mixture was heated externally to a refluxing point at 3 minutes. The reaction conditions and weight average molecular weights of the isolated polymers are shown in Table 2. TABLE 2 mol % Initial % Mw Example triethylamine Comments^(a) Reflux^(b) Mw^(c) Retention^(d) 12 4   1% PhOH Y 19.5 99 13 4  15% excess N 19.9 100 Rs 14 4 0.5% PhOH N 21.6 99.5 15 4  15% excess Y 21.8 96.6 Rs 16 4   1% PhOH N 21.9 99.3 17 4   1% PhOH Y 22.2 97.7 18 4 N 22.3 96.1 19 4  13% excess N 22.4 97.7 Rs 20 4   1% PhOH Y 22.4 96.4 21 4   1% PhOH Y 22.5 93 22 4   1% PhOH N 22.7 97.8 23 4 0.5 PhCOCl N 24.6 99 24 2.5   1% PhOH Y 24.7 97.2 25 4 N 24.8 96.7 26 4 Y 25.3 98 27 4 N 26.6 97.7 28 3 Y 30.3 100

EXAMPLES 29-46

[0128] The procedure of Examples 2-11 was repeated except that a portion of tertiary amine was added following addition of dicarboxylic acid dichloride to resorcinol moiety. A total of 4 mol % tertiary amine (40000 ppm; based on moles acid chlorides) was added. The reaction conditions and weight average molecular weights of the isolated polymers are shown in Table 3. Example 46 is a control experiment in which all the tertiary amine was present at the beginning of the reaction before addition of dicarboxylic acid dichloride to resorcinol moiety TABLE 3 % Base Base TEA added Added in Addition initially Initial % Mw Example 1st Step time (min.) (ppm) Mw^(a) Retention^(b) 29 80 7 50 29.3 96.5 30 80 7 10 23.1 86.8 31 80 7 10 22.2 98.5 32 80 7 50 29.4 97.4 33 96 7 10 32.7 94.3 34 96 7 50 34.4 92.5 35 88 10 30 26.5 99.4 36 88 10 30 25.6 101 37 80 13 50 25.9 95.9 38 80 13 10 25.2 96.6 39 96 13 50 29.4 90.2 40 96 13 10 22.14 98.59 41 96 13 50 26.7 92.93 42 96 13 10 23.6 90.5 43 96 16 10 21.6, 98.8, 22.0 98.0 44 96 19 10 24.1, 95.9, 22.3 97.3 45 64 7 10 21.46, 96.3, 23.31 100 46 96 16 40000 24.7, 92.7, 23.1 94.4

EXAMPLE 47

[0129] This example illustrates the preparation of a thermally stable resorcinol iso/terephthalate-block-copolycarbonate beginning with the preparation of hydroxy-terminated resorcinol iso/terephthalate oligomer. To a thirty liter glass reactor equipped with a glass impeller, centrifuge recirculation pump, reflux condenser and pressure-equilibration addition funnel were charged resorcinol (605.6 g, 5.5 mol), methyltributylammonium chloride (82.5 g of a 75 wt. % aqueous solution; 0.275 mol), dichloromethane (6.5 liters), and water (2.5 liters). The recirculation pump was turned on and the mixture was degassed with nitrogen while stirring. The pH of the aqueous phase was adjusted to 7 with 50% aqueous sodium hydroxide solution. Reaction was carried out by adding a solution of acid chlorides (507.5 g each of iso- and terephthaloyl dichlorides; 5.00 moles total in 2.0 liters of dichloromethane solution) while stirring and simultaneously adding 50% sodium hydroxide solution at such a rate that the pH was maintained between 6 and 8. The acid chlorides were added using a three-step program with the rate of addition declining with each step. A timer was started at the beginning of acid chloride addition. The pH was maintained at 8 while adding acid chlorides over 8 minutes using the following protocol: 40% of total acid chlorides was added over the first 2 minutes; 30% of total was added over the next 2 minutes; the remaining 30% of total was added over the next 4 minutes. The recirculation loop was running during the entire time.

[0130] Following complete addition of acid chlorides, the pH was slowly raised to 11-12 over two to three minutes, and the reaction mixture was stirred for 10 minutes. The polymer formed was a hydroxy-terminated oligomer with weight average molecular weight (Mw) of approximately 20,000.

[0131] Bisphenol A (1102 g, 4.83 mol), dichloromethane (4.0 liters), triethylamine (17 ml, 0.12 mol), p-cumyl phenol capping agent (60 g), and water (6.0 liters) were then added and the recirculation loop was turned on. Phosgene was introduced at pH 7.5-8.5, then increasing slowly to pH 10-10.5 using a 15% excess over the theoretical amount of phosgene.

[0132] The reaction mixture was separated, the organic phase washed with IN hydrochloric acid, 0.1N hydrochloric acid, and twice with water, and the polymer was isolated by precipitation in methanol. The polymer obtained was the desired resorcinol iso/terephthalate-co-BPA polycarbonate copolymer.

EXAMPLES 48-61

[0133] Samples of polymers comprising resorcinol arylate polyester chain members were dried in vacuo at 120° C. for 15 hrs. A weighed sample of about 25-30 milligrams was placed in a circular die cavity 2 centimeters (cm.) in diameter and covered with a cylindrical piston of the same size. The die assembly containing the sample was heated in a Carver press at 290° C. for 5 minutes at 500-4,000 pounds gauge (lbs.g.) pressure, then removed and cooled in chill blocks. The heat treatment produced a film about 1 mil in thickness and 2 cm. in diameter. Molecular weights of samples before and after the heat treatment were measured by GPC using polystyrene standards. Table 4 shows examples of melt stability for resorcinol arylate polyesters prepared using the method of Example 1 and Control Examples 1 and 2, and for resorcinol arylate-containing copolyestercarbonates prepared using the method of Example 47. Wt. % resorcinol arylate in the Table refers to the approximate wt. % resorcinol arylate chain members in the polymer, the remaining mers being organic carbonate mers. TABLE 4 wt. % % Mw resorcinol % Mw Retention, Retention, Example arylate melt test amine test^(f) 48^(a) 50 89.4 98 49^(a) 80 84 97.9 50^(a) 50 84.8 94 51^(b) 50 98.8 99.5 52^(b) 35 98.7 99.3 53^(a) 100 55 62 54^(a) 100 55.9 61 55^(a) 100 45 40 56^(b) 100 87.5 86 57^(b) 100 97.7 99.6 58^(b) 100 99.5 99 59^(c) 100 12 25 60^(d) 100 46 74 61^(e) 100 77 78

EXAMPLE 62

[0134] A resorcinol arylate polyester was prepared by the interfacial method of Control Example 1 except that the organic solvent was dichloromethane and a capping agent was present. Extrusion of the material gave orange pellets. The polymer had initial weight average molecular weight (Mw) of 61,300 and Mw after extrusion of 52,200 (85% retention). A separate sample of material was treated with dibutylamine in solution; the Mw of the recovered material was 42,400 (69% retention).

EXAMPLE 63

[0135] A resorcinol arylate polyester was prepared by the method of Example 1. Extrusion of the material gave yellowish pellets. The polymer had initial Mw of 53,600 and Mw after extrusion of 50,800 (95% retention). A separate sample of material was treated with dibutylamine in solution; the Mw of the recovered material was 48,400 (90% retention).

EXAMPLE 64

[0136] A resorcinol arylate-containing block copolyester-carbonate with about 50% by weight carbonate blocks and 1:1 ratio of isophthalate to terephthalate in the resorcinol arylate blocks was prepared by the method of Example 47 except that the resorcinol arylate-containing polyester block was made using the procedure of Control Example 1 using a capping agent-and dichloromethane as the organic solvent. Extrusion of the material gave amber pellets. The copolymer had initial Mw of 75,900 and Mw after extrusion of 64,500 (85% retention). A separate sample of material was treated with dibutylamine in solution; the Mw of the recovered material was 73,000 (96% retention).

EXAMPLE 65

[0137] A resorcinol arylate-containing block copolyester-carbonate was prepared by the method of Example 47 with about 50% by weight carbonate blocks and 1:1 ratio of isophthalate to terephthalate in the resorcinol arylate blocks. Extrusion of the material gave faintly yellowish pellets. The copolymer had initial Mw of 52,300 and Mw after extrusion of 51,700 (99% retention). A separate sample of material was treated with dibutylamine in solution; the Mw of the recovered material was 51,500 (98% retention).

[0138] Disks were formed from the resorcinol arylate-containing polymers of Examples 62-65. The disks were approximately 0.6 millimeters (mm) (0.024 inches) thick and 50 mm (2.0 inches) diameter, and were formed from melt-processed polymer (either pellets, extruded film, or injection molded parts) under the following conditions: 2.1 g of melt-processed polymer were placed in a mold between heated platens of a hydraulic press and heated at about 200° C. with no applied pressure for 3 minutes, then under 4500 lbs.g. pressure for 1 minute, and finally under 6500 lbs.g. pressure for 1 minute. The mold was then rapidly cooled in ice water and opened to remove the disk.

[0139] The disks prepared as described were laminated onto injection-molded plaques of LEXAN 140 polycarbonate (from General Electric Plastics) containing 2 wt. % of titanium dioxide pigment under the following conditions to make well-adhered multilayer articles. All materials were placed in a heated (60° C.) vacuum desiccator overnight. A disk was placed onto an injection molded plaque of polycarbonate 2.5 inches square and one-eighth inch thick in a mold between heated platens of a hydraulic press and heated at about 200° C. with no applied pressure for 2 minutes, then under 4500 lbs. gauge pressure for 1 minute, and finally under 6500 lbs. gauge pressure for 1 minute. All samples were well adhered.

[0140] The color of the disks and of the laminated plaques was determined on a GretagMcbeth™ Color-Eye 7000A calorimeter and reported as CIELAB values and yellowness index (YI; according to ASTM D1925). Results are shown on Table 5. TABLE 5 Disks (transmission) Laminate on PC (reflection) Example L* a* b* YI L* a* b* YI 62 90.45 −1.23 15.2 26.01 76.6 3.57 31.74 61.07 63 94.73 −0.3 3.61 6.34 86.18 −0.38 14.95 27.4 64 93.82 −0.43 5.4 9.5 84.21 0.88 20.44 38.27 65 95.52 −0.11 1.31 2.26 91.21 −0.8 6.95 12 unlaminated 94.86 −0.52 2.88 4.51 PC

[0141] The data show that the disks and multilayer articles formed from melt-processed resorcinol arylate-containing polymers made by a method of the invention have much less color and lower yellowness index than the respective control blends.

EXAMPLES 66-74

[0142] In these Examples all the resorcinol arylate polymers comprised structural units derived from resorcinol and a 1:1 mixture of iso- and terephthaloyl dichlorides. The Examples used either a resorcinol arylate polyester (Polymer A) or a resorcinol arylate block copolymer with bisphenol A polycarbonate (Polymer B with about 30 wt. % carbonate units, or Polymer C with about 50 wt. % carbonate units). As stabilizer additives, UV absorbers (“UVA”) available from Cytec Corp. were employed: CYASORB 5411 (UVA 1), CYASORB 531 (UVA 2), and CYASORB 1164 (UVA 3). Films were cast from resorcinol arylate-comprising polymer by dissolving 2 grams of the polymer and any auxiliary UV absorber in 8 milliliters of chloroform. The solution was drawn onto a glass plate using 12 mil doctor blade and allowed to dry in air resulting in a film about 40 microns thick. The films were laminated onto injection-molded plaques of LEXAN polycarbonate (from General Electric Plastics) containing 2 wt. % of titanium dioxide pigment under the following conditions to make multilayer articles. Two layers of these films were placed on top of injection molded plaques comprising LEXAN, and the assembly was placed in a Carver press. The sample in the press was heated at about 210° C. with no applied pressure for 2 minutes, under 4500 lbs. gauge pressure for 1 minute, and finally under 6500 lbs. gauge pressure for 1 minute. The films were well adhered to the substrates. The samples were exposed to weathering in an Atlas Ci4000 xenon arc weatherometer equipped with borosilicate inner and outer filters at an irradiance of 0.77 watts per square meter at 340 nanometers. Exposure conditions were black panel 63° C., dry bulb 43° C., humidity 30%, continuous illumination. The cycle was 102 minutes light followed by 18 minutes with water spray. Samples were evaluated for color on a GretagMacbeth™ Color-Eye 7000A colorimeter with results reported as ΔE ((ΔE=ΔL²+Δa²+Δb²)^(1/2)) and change in yellowness index (ΔYI; according to ASTM D1925). Exposure was measured in kilojoules per square meter of energy received at 340 nanometers. Results are shown in Table 6. The amount of UVA was based on total solids. TABLE 6 UV ΔYI at ΔYI at ΔE at Example Polymer Absorber Initial YI 242 kJ/m² 1127 kJ/m² 1127 kJ/m² 66 A none 5.49 11.02 12.76 10.37 67 A 1% UVA 1 6.06 8.74 10.57 8.66 68 B none 4.63 9.43 11.62 9.26 69 B 1% UVA 1 4.91 7.53 9.89 7.92 70 B 5% UVA 1 5.77 4.52 6.92 5.61 71 B 1% UVA 2 5.48 7.21 9.68 7.65 72 B 1% UVA 3 5.52 7.52 9.84 7.92 73 C none 4.73 8.66 11.80 9.18 74 C 1% UVA 1 5.08 7.31 9.96 7.87

[0143] In each case the use of 1% UVA reduced the amount of yellowing by about 15%, while the use of 5% UVA reduced the amount of yellowing by about 40%.

EXAMPLES 75-82

[0144] In these Examples the resorcinol arylate polymer comprised structural units derived from resorcinol and a 1:1 mixture of iso- and terephthaloyl dichlorides. The Examples used a resorcinol arylate block copolymer with bisphenol A polycarbonate containing about 15 wt. % carbonate units. As stabilizer additives, commercial stabilizers were employed, sometimes in combination with phosphorous acid. Phosphorous acid was employed as a 45 wt. % solution in deionized water. Stabilizer additives were mixed with block copolymer before extrusion using a single-screw extruder. The extruded mixture was molded into plaques about one-eighth inch thick. The color of the disks was determined and reported as yellowness index (YI; according to ASTM D1925). The results are shown in Table 7. The amounts of stabilizer used are reported in parts based on 100 parts resin (phr). TABLE 7 Example Stabilizer additive (phr) Initial YI 75 none 17.2 76 Bis(2,4-dicumylphenyl)pentaerythritol 12.9 diphosphite (0.03) 77 Bis(2,4-dicumylphenyl)pentaerythritol 9.2 diphosphite (0.1) 78 Bis(2,4-dicumylphenyl)pentaerythritol 9.9 diphosphite (0.1) + deionized water (0.1) 79 Bis(2,4-dicumylphenyl)pentaerythritol 8.5 diphosphite (0.05) + phosphorous acid (0.005) 80 Bis(2,4-dicumylphenyl)pentaerythritol 7.1 diphosphite (0.1) + phosphorous acid (0.005) 81 Bis(2,4-dicumylphenyl)pentaerythritol 7.0 diphosphite (0.15) + phosphorous acid (0.005) 82 Bis(2,4-dicumylphenyl)pentaerythritol 6.9 diphosphite (0.1) + phosphorous acid (0.01)

[0145] In each case the addition of phosphite stabilizer alone or in combination with phosphrous acid reduced the initial YI.

EXAMPLE 83

[0146] A resorcinol, arylate block copolymer with bisphenol A polycarbonate as described in Examples 75-82 was mixed with 0.0005 phr phosphorous acid and 0.1 phr bis(2,4-dicumylphenyl)pentaerythritol diphosphite using the method described in Examples 75-82. Molded plaques showed YI of 8.3.

EXAMPLE 84

[0147] A resorcinol arylate block copolymer with bisphenol A polycarbonate as described in Examples 75-82 was mixed with 0.005 phr phosphorous acid and 0.1 phr tris(2,4-di-tert-butylphenyl)phosphite using the method described in Examples 75-82. Molded plaques showed YI of 7.4.

EXAMPLE 85

[0148] A resorcinol arylate block copolymer with bisphenol A polycarbonate as described Examples 75-82 was mixed with 0.005 phr phosphorous acid, 0.07 phr tris(2,4-di-tert-butylphenyl)phosphite, and 0.03 phr of a hindered phenol stabilizer using the method described in Examples 75-82. Molded plaques showed YI of 7.7.

EXAMPLE 86

[0149] In this Example the resorcinol arylate polymer comprised structural units derived from resorcinol and a 1:1 mixture of iso- and terephthaloyl dichlorides. The Example used a resorcinol arylate block copolymer with bisphenol A polycarbonate containing about 25 wt. % carbonate units. As stabilizer additive, phosphorous acid was employed as 10 wt. % solution in deionized water which was mixed with the block copolymer before extrusion using a twin-screw extruder. The extruded mixture was molded into plaques 2.5 inches square and one-eighth inch thick. The color of the disks was determined on a GretagMacbeth™ Color-Eye 7000A calorimeter and reported as yellowness index (YI; according to ASTM D1925). A plaque containing 0.2 wt. % phosphorous acid had an initial YI of 11.1. For comparison a similar plaque made without phosphorous acid had an initial YI of 20.1.

EXAMPLES 87-100

[0150] In these Examples the resorcinol arylate polymer comprised a resorcinol arylate block copolymer with bisphenol A polycarbonate containing about 10 wt. % carbonate units. The resorcinol arylate structural units were derived from resorcinol and a 1:1 mixture of iso- and terephthaloyl dichlorides. As stabilizer additives, UV absorbers (“UVA”) were employed: CYASORB 5411 available from Cytec Corp. (UVA 1); CYASORB UV-3638 available from Cytec Corp. (UVA 4); and UVINUL 3030 available from BASF Corp. (UVA 5). Table 8 shows physical properties for molded parts of compositions containing various amounts of stabilizer additive. The value for “wt. % UVA detected” was determined by UV spectroscopy on a sample of copolymer recovered from a molded part. The value for “Mw in molded part” was weight average molecular weight determined on a sample of copolymer recovered from a molded part. Melt volume rate (MVR) was determined using ASTM D1238.

[0151] Notched Izod impact strength was determined using ASTM D256. Initial viscosity was determined at a frequency of 10 radians per second using a Rheometrics Dynamic Spectrometer. TABLE 8 % Mw MVR @ MVR @ Initial Viscosity Notched Notched wt. % wt. % Mw in change 300° C.; 300° C.; viscosity @ drop after Izod @ Izod @ UVA UVA molded relative to 6 min. dwell; 18 min. dwell; 300° C. 30 min. @ 0° C.; 23° C. Example added detected part powder cc/10 min. cc/10 min. poise 300° C. J/m J/m 87; UVA1 0 0 22344 −4.4 4.19 — 12499 +0.3 437 805 88; UVA1 0.3 0.07 22530 −3.6 5.48 — 9555 −11 187 688 89; UVA1 1 0.45 19834 −15.2 8.54 — 6685 −35 21 197 90; UVA1 5 3.23 16959 −27.5 7.02 — 2131 −69 21 43 91; UVA4 0 0 24638 0 4.11 4.16 12124 +1 — 693 92; UVA4 1 0.93 24388 −0.9 4.60 4.62 11221 +0.3 — 480 93; UVA4 3 2.64 24487 −0.5 5.56 5.53 9432 +2.4 — 117 94; UVA4 5 4.33 24547 −0.3 6.44 6.45 8161 +4.5 — 53 95; UVA5 0 0 24005 −2.5 4.71 5.11 12725 +2.1 — 757 96; UVA5 0.3 0.3 24005 −2.5 4.46 4.65 12922 +3 — 650 97; UVA5 1 0.98 24101 −2.1 4.75 4.87 12067 −0.5 — 666 98; UVA5 3 2.88 24307 −1.3 5.23 5.61 10410 −6.3 — 469 99; UVA5 5 4.7 24398 −0.9 6.20 6.70 9213 −11 — 128 100; UVA5  8 7.15 24286 −1.4 7.37 8.63 7375 −24 — 69

[0152] The data in Table 8 show that both CYASORB UV-3638 and UVINUL 3030 are detected in higher amounts in molded compositions than is CYASORB 5411. The data also show that compositions containing CYASORB UV-3638 or UVINUL 3030 had better retention of copolymer molecular weight in molded parts than do compositions containing CYASORB 5411. Although the invention is in no way dependent upon any theory of operation, it is believed that some UVA may be lost through volatilization during an extrusion compounding step and also through reaction with copolymer.

EXAMPLES 101-109

[0153] In these Examples the resorcinol arylate polymer comprised a resorcinol arylate block copolymer with bisphenol A polycarbonate containing about 10 wt. % carbonate units. The resorcinol arylate structural units were derived from resorcinol and a 1:1 mixture of iso- and terephthaloyl dichlorides: As stabilizer additives, UV absorbers (“UVA”) were employed: CYASORB 5411 available from Cytec Corp. (UVA 1); CYASORB UV-3638 available from Cytec Corp. (UVA 4); and UVINUL 3030 available from BASF Corp. (UVA 5). Table 9 shows physical properties for molded parts of compositions containing various amounts of stabilizer additive and either phosphorous acid or the bis-epoxide, 3,4-epoxycyclohexylmethyl-3′,4′-epoxycyclohexanecarboxylate. Values for phosphorous acid refer to parts per hundred parts resin (phr) of 45 wt. % aqueous phosphorous acid solution. The value for “Mw in molded part” was weight average molecular weight determined on a sample of copolymer recovered from a molded part. Melt volume rate (MVR) was determined using ASTM D1238. The color of the disks was determined on 0.125 inch thick color chips at transmission mode and reported as yellowness index (YI; according to ASTM D 1925). TABLE 9 H₃PO₃ % Mw MVR @ MVR @ solution epoxide Mw in change 300° C.; 300° C.; added, added, molded relative to 6 min. dwell; 18 min. dwell; Example phr phr part powder cc/10 min. cc/10 min. YI 101; UVA1 — — 21429 −13 8.19 9.98 14.0 102; UVA1 0.005 — 23260 −5.5 5.88 6.79 11.0 103; UVA1 — 0.1 20464 −16.9 11.4 12.6 17.8 104; UVA4 — — 24388 −0.95 4.60 4.62 12.4 105; UVA4 0.005 — 23220 −5.69 5.24 5.54 8.73 106; UVA4 — 0.1 25073 +1.84 4.27 4.57 17.5 107; UVA5 — — 24101 −2.11 4.75 4.87 11.7 108; UVA5 0.005 — 23167 −5.91 5.76 5.76 8.50 109; UVA5 — 0.1 24421 −0.81 4.15 4.86 14.7

[0154] The data in Table 9 show that improved color was obtained using the combination of phosphorous acid and UVA. The data also show that improved molecular weight retention was obtained using the combination of epoxide and UVA, at least when the UVA is either of CYASORB UV-3638 or UVINUL 3030.

EXAMPLES 110-111

[0155]FIG. 1 shows a graph of delta E vs. exposure in CIRA/sodalime xenon arc lamp for a molded disk containing UVINUL 3030 and a resorcinol arylate block copolymer with bisphenol A polycarbonate containing about 10 wt. % carbonate units. The resorcinol arylate structural units were derived from resorcinol and a 1:1 mixture of iso- and terephthaloyl dichlorides. The disk comprising a 10 mil layer of copolymer laminated onto a layer of white bisphenol A polycarbonate. The data were collected under conditions similar to those of Examples 66-74 except using a CIRA inner filter and a sodalime outer filter. The data show that the magnitude of delta E is decreased with increasing amount of UVINUL 3030 in the coating layer.

[0156]FIG. 2 shows a graph of delta E vs. exposure in boro/boro xenon arc lamp for a molded disk containing CYASORB UV-3638 and a resorcinol arylate block copolymer with bisphenol A polycarbonate containing about 20 wt. % carbonate units. The resorcinol arylate structural units were derived from resorcinol and a 1:1 mixture of iso- and terephthaloyl dichlorides. The disk comprising a 10 mil layer of copolymer laminated onto a layer of white bisphenol A polycarbonate. The data were collected under conditions similar to those of Examples 66-74. The data show that the magnitude of delta E is decreased with increasing amount of CYASORB UV-3638 in the coating layer.

EXAMPLES 112-115

[0157] In these Examples the resorcinol arylate polymer comprised a resorcinol arylate block copolymer with bisphenol A polycarbonate containing about 10 wt. % carbonate units. The resorcinol arylate structural units were derived from resorcinol and a 1:1 mixture of iso- and terephthaloyl dichlorides. As stabilizer additives, there were employed bis(2,4-dicumylphenyl pentaerythritol) diphosphite (obtained as DOVERPHOS S9228 from Dover Chemical Corporation and referred to in Table 10 as “diphosphite”) and 3,4-epoxycyclohexylmethyl-3′,4′-epoxycyclohexanecarboxylate. Table 10 shows physical properties for molded parts of compositions containing various amounts of stabilizer additives following autoclaving at 105° C. Change in % haze (delta % haze) and change in YI values (delta YI) were determined according to ASTM D1925 on one-eighth inch thick molded parts. Changes in weight average molecular weights were determined by GPC. TABLE 10 Example 112 113 114 115 diphosphite, phr 0.03 0.03 0.03 0.03 epoxide, phr 0 0.03 0.06 0.10 delta YI  25 hrs. 0 0 0 0  50 hrs. 3 1 1 1  75 hrs. 9 2 2 2  90 hrs. 14 3 3 3 140 hrs. 18 5 5 5 % Mw loss  25 hrs. 10 2 2 2  50 hrs. 24 3 3 3  75 hrs. 34 5 5 5  90 hrs. 47 9 9 9 140 hrs. 67 11 11 11 delta % haze  25 hrs. 2 2 2 2  50 hrs. 18 9 9 9  75 hrs. 39 13 13 13  90 hrs. 64 19 19 19 140 hrs. 81 30 30 30

[0158] The data show that changes in YI, molecular weight, and % haze in molded parts are decreased in the presence of diphosphite stabilizer and epoxy additives.

EXAMPLES 116-123

[0159] In these Examples the resorcinol arylate polymer comprised a resorcinol arylate block copolymer with bisphenol A polycarbonate containing various wt. % levels of carbonate units. The resorcinol aryl ate structural units were derived from resorcinol and a 1:1 mixture of iso- and terephthaloyl dichiorides. As stabilizer additives, UV absorbers were employed: CYASORB UV-3638 available from Cytec Corp.; and UVINUL 3030 available from BASF Corp. Table 11 shows values for delta E vs. exposure in CIRA/sodalime xenon arc lamp for injection molded parts of compositions containing various amounts of stabilizer additives. The parts were transparent plaques one-eighth inch thick. The data were collected under conditions similar to those of Examples 66-74 except using a CIRA inner filter and a sodalime outer filter. TABLE 11 UVINUL UV- 3030 3638 Delta E at Example wt. % PC phr phr 3284 kJ/m² 6179 kJ/m² 116 70 — — 4.14 4.81 117 70 2 — 1.46 1.32 118 80 — — 4.32 5.02 119 80 — 1 1.72 2.20 120 80 1 — 2.30 2.54 121 80 2 — 1.32 1.93 122 90 — 3.72 4.03 123 90 2 1.51 1.49

[0160] The data show that changes in delta E in molded parts are decreased in the presence of UVINUL 3030 and CYASORB UV-3638.

[0161] While the invention has been illustrated and described in typical embodiments, it is not intended to be limited to the details shown, since various modifications and substitutions can be made without departing in any way from the spirit of the present invention. As such, further modifications and equivalents of the invention herein disclosed may occur to persons skilled in the art using no more than routine experimentation, and all such modifications and equivalents are believed to be within the spirit and scope of the invention as defined by the following claims. All U.S. patents and patent applications cited herein are incorporated herein by reference. 

What is claimed is:
 1. A composition comprising (a) a thermally stable polymer comprising resorcinol arylate polyester chain members substantially free of anhydride linkages linking at least two mers of the polymer chain, and (b) at least one auxiliary stabilizer additive selected from the group consisting of 2,2′-(1,4-phenylene)bis(4H-3,1-benzoxazin-4-one) and 1,3-bis[(2-cyano-3,3-diphenylacryloyl)oxy]-2,2-bis[[(2-cyano-3,3-diphenylacryloyl)oxy]methyl]propane.
 2. The composition of claim 1 further comprising at least one auxiliary stabilizer additive selected from the group consisting of a hindered phenol, an epoxide, a phosphite, and phosphorous acid, and mixtures thereof
 3. A unitary or multilayer article comprising the composition of claim
 1. 4. A unitary or multilayer article comprising the composition of claim
 2. 5. The article of claim 3 which is a unitary article.
 6. A multilayer article comprising: a substrate layer comprising at least one thermoplastic polymer, thermoset polymer, cellulosic material, glass, or metal, and at least one coating layer thereon, said coating layer comprising the composition of claim
 1. 7. The article according to claim 6 wherein the substrate comprises at least one homo- or copolymeric aliphatic olefin or functionalized olefin polymer, polycarbonate, polyester or addition polymer of an alkenylaromatic compound.
 8. The article according to claim 7 wherein the substrate comprises at least one polyolefin homopolymer, polyethylene, polypropylene, thermoplastic polyolefin, bisphenol A homo- or copolycarbonate, poly(alkylene terephthalate), or ABS or ASA copolymer.
 9. The article according to claim 6 wherein the coating layer further comprises at least one colorant.
 10. The article according to claim 6 wherein the substrate contains at least one of fillers and colorants.
 11. The article according to claim 6 further comprising at least one intermediate layer disposed between said coating and substrate layers.
 12. The article according to claim 11 wherein at least one intermediate layer is an adhesive layer.
 13. The article according to claim 11 wherein the intermediate layer contains at least one of fillers and colorants.
 14. The article according to claim 6 wherein said multilayer article is further applied to a substrate layer.
 15. The method according to claim 14 wherein the substrate layer comprises at least one homo- or copolymeric aliphatic olefin or functionalized olefin polymer, polycarbonate, polyester or addition polymer of an alkenylaromatic compound.
 16. The article according to claim 3 which is an aircraft, automotive, truck, military vehicle, military aircraft, military water-borne vehicle, scooter, or motorcycle exterior or interior component, panel, quarter panel, rocker panel, trim, fender, door, decklid, trunklid, hood, bonnet, roof, bumper, fascia, grill, mirror housing, pillar applique, cladding, body side molding, wheel cover, hubcap, door handle, spoiler, window frame, headlamp bezel, headlamp, tail lamp, tail lamp housing, tail lamp bezel, license plate enclosure, roof rack, or running board; an enclosure, housing, panel, part, or trim for an outdoor vehicle or device, an electrical or telecommunication device, network interface device, outdoor furniture, aircraft, boat or marine equipment, outboard motor, depth finder, personal water-craft, jet-ski, pool, spa, hot-tub, step, step covering, automatic teller machine (ATM), lawn or garden tractor, lawn mower, tool, lawn or garden tool, sporting equipment, toy, snowmobile, recreational vehicle, golf course marker, or playground equipment; an enclosure, housing, panel, part, or trim for a computer, desk-top computer, portable computer, lap-top computer, palm-held computer, monitor, printer, keyboard, FAX machine, copier, telephone, mobile phone, phone bezel, radio sender, radio receiver, meter, antenna, light fixture, lighting appliance, transformer, or air conditioner; an article used in building or construction, glazing, roofing, window, window trim, floor, wall panel, door, door trim, countertop, decorative window furnishing or treatment; a treated glass cover for a picture, painting, poster, or display item; a protected graphic; an outdoor or indoor sign; optical lens; ophthalmic lens; corrective ophthalmic lens; implantable ophthalmic lens; refractor; sheath for fluorescent tube; sleeve guard; an article made from a plastic-wood combination; a utility pit cover; shoe lace; cladding or seating for public transportation; cladding or seating for trains, subways, or buses; cladding for satellite dishes; coated helmet or personal protective equipment; coated synthetic or natural textiles; coated photographic film or photographic print; coated painted article; coated dyed article; coated fluorescent article; or coated foam article.
 17. A composition comprising (a) a thermally stable polymer consisting essentially of resorcinol arylate polyester chain members substantially free of anhydride linkages linking at least two mers of the polymer chain, and (b) at least one auxiliary stabilizer additive selected from the group consisting of 2,2′-(1,4-phenylene)bis(4H-3,1-benzoxazin-4-one) and 1,3-bis[(2-cyano-3,3-diphenylacryloyl)oxy]-2,2-bis[[(2-cyano-3,3-diphenylacryloyl)oxy]methyl]propane.
 18. The composition of claim 17 further comprising at least one auxiliary stabilizer additive selected from the group consisting of a hindered phenol, an epoxide, a phosphite, and phosphorous acid, and mixtures thereof
 19. A unitary or multilayer article comprising the composition of claim
 17. 20. A unitary or multilayer article comprising the composition of claim
 18. 21. The article of claim 19 which is a unitary article.
 22. A multilayer article comprising: a substrate layer comprising at least one thermoplastic polymer, thermoset polymer, cellulosic material, glass, or metal, and at least one coating layer thereon, said coating layer comprising the composition of claim
 17. 23. The article according to claim 22 wherein the substrate comprises at least one homo- or copolymeric aliphatic olefin or functionalized olefin polymer, polycarbonate, polyester or addition polymer of an alkenylaromatic compound.
 24. The article according to claim 23 wherein the substrate comprises at least one polyolefin homopolymer, polyethylene, polypropylene, thermoplastic polyolefin, bisphenol A homo- or copolycarbonate, poly(alkylene terephthalate), or ABS or ASA copolymer.
 25. The article according to claim 22 wherein the coating layer further comprises at least one colorant.
 26. The article according to claim 22 wherein the substrate contains at least one of fillers and colorants.
 27. The article according to claim 22 further comprising at least one intermediate layer disposed between said coating and substrate layers.
 28. The article according to claim 27 wherein at least one intermediate layer is an adhesive layer.
 29. The article according to claim 27 wherein the intermediate layer contains at least one of fillers and colorants.
 30. The article according to claim 22 wherein said multilayer article is further applied to a substrate layer.
 31. The method according to claim 30 wherein the substrate layer comprises at least one homo- or copolymeric aliphatic olefin or functionalized olefin polymer, polycarbonate, polyester or addition polymer of an alkenylaromatic compound.
 32. The article according to claim 19 which is an aircraft, automotive, truck, military vehicle, military aircraft, military water-borne vehicle, scooter, or motorcycle exterior or interior component, panel, quarter panel, rocker panel, trim, fender, door, decklid, trunklid, hood, bonnet, roof, bumper, fascia, grill, mirror housing, pillar applique, cladding, body side molding, wheel cover, hubcap, door handle, spoiler, window frame, headlamp bezel, headlamp, tail lamp, tail lamp housing, tail lamp bezel, license plate enclosure, roof rack, or running board; an enclosure, housing, panel, part, or trim for an outdoor vehicle or device, an electrical or telecommunication device, network interface device, outdoor furniture, aircraft, boat or marine equipment, outboard motor, depth finder, personal water-craft, jet-ski, pool, spa, hot-tub, step, step covering, automatic teller machine (ATM), lawn or garden tractor, lawn mower, tool, lawn or garden tool, sporting equipment, toy, snowmobile, recreational vehicle, golf course marker, or playground equipment; an enclosure, housing, panel, part, or trim for a computer, desk-top computer, portable computer, lap-top computer, palm-held computer, monitor, printer, keyboard, FAX machine, copier, telephone, mobile phone, phone bezel, radio sender, radio receiver, meter, antenna, light fixture, lighting appliance, transformer, or air conditioner; an article used in building or construction, glazing, roofing, window, window trim, floor, wall panel, door, door trim, countertop, decorative window furnishing or treatment; a treated glass cover for a picture, painting, poster, or display item; a protected graphic; an outdoor or indoor sign; optical lens; ophthalmic lens; corrective ophthalmic lens; implantable ophthalmic lens; refractor; sheath for fluorescent tube; sleeve guard; an article made from a plastic-wood combination; a utility pit cover; shoe lace; cladding or seating for public transportation; cladding or seating for trains, subways, or buses; cladding for satellite dishes; coated helmet or personal protective equipment; coated synthetic or natural textiles; coated photographic film or photographic print; coated painted article; coated dyed article; coated fluorescent article; or coated foam article.
 33. A composition comprising (a) a thermally stable copolymer comprising resorcinol arylate polyester chain members in combination with C₃₋₂₀ straight chain alkylene, C₃₋₁₀ branched alkylene, or C₄₋₁₀ cyclo- or bicyclo-alkylene chain members, substantially free of anhydride linkages linking at least two mers of the polymer chain, and (b) at least one auxiliary stabilizer additive selected from the group consisting of 2,2′-(1,4-phenylene)bis(4H-3,1-benzoxazin-4-one) and 1,3-bis[(2-cyano-3,3-diphenylacryloyl)oxy]-2,2-bis[[(2-cyano-3,3-diphenylacryloyl)oxy]methyl]propane.
 34. The composition of claim 33 further comprising at least one auxiliary stabilizer additive selected from the group consisting of a hindered phenol, an epoxide, a phosphite, and phosphorous acid, and mixtures thereof
 35. A unitary or multilayer article comprising the composition of claim
 33. 36. A unitary or multilayer article comprising the composition of claim
 34. 37. The article of claim 35 which is a unitary article.
 38. A multilayer article comprising: a substrate layer comprising at least one thermoplastic polymer, thermoset polymer, cellulosic material, glass, or metal, and at least one coating layer thereon, said coating layer comprising the composition of claim
 33. 39. The article according to claim 38 wherein the substrate comprises at least one homo- or copolymeric aliphatic olefin or functionalized olefin polymer, polycarbonate, polyester or addition polymer of an alkenylaromatic compound.
 40. The article according to claim 39 wherein the substrate comprises at least one polyolefin homopolymer, polyethylene, polypropylene, thermoplastic polyolefin, bisphenol A homo- or copolycarbonate, poly(alkylene terephthalate), or ABS or ASA copolymer.
 41. The article according to claim 38 wherein the coating layer further comprises at least one colorant.
 42. The article according to claim 38 wherein the substrate contains at least one of fillers and colorants.
 43. The article according to claim 38 further comprising at least one intermediate layer disposed between said coating and substrate layers.
 44. The article according to claim 43 wherein at least one intermediate layer is an adhesive layer.
 45. The article according to claim 43 wherein the intermediate layer contains at least one of fillers and colorants.
 46. The article according to claim 38 wherein said multilayer article is further applied to a substrate layer.
 47. The method according to claim 46 wherein the substrate layer comprises at least one homo- or copolymeric aliphatic olefin or functionalized olefin polymer, polycarbonate, polyester or addition polymer of an alkenylaromatic compound.
 48. The article according to claim 35 which is an aircraft, automotive, truck, military vehicle, military aircraft, military water-borne vehicle, scooter, or motorcycle exterior or interior component, panel, quarter panel, rocker panel, trim, fender, door, decklid, trunklid, hood, bonnet, roof, bumper, fascia, grill, mirror housing, pillar applique, cladding, body side molding, wheel cover, hubcap, door handle, spoiler, window frame, headlamp bezel, headlamp, tail lamp, tail lamp housing, tail lamp bezel, license plate enclosure, roof rack, or running board; an enclosure, housing, panel, part, or trim for an outdoor vehicle or device, an electrical or telecommunication device, network interface device, outdoor furniture, aircraft, boat or marine equipment, outboard motor, depth finder, personal water-craft, jet-ski, pool, spa, hot-tub, step, step covering, automatic teller machine (ATM), lawn or garden tractor, lawn mower, tool, lawn or garden tool, sporting equipment, toy, snowmobile, recreational vehicle, golf course marker, or playground equipment; an enclosure, housing, panel, part, or trim for a computer, desk-top computer, portable computer, lap-top computer, palm-held computer, monitor, printer, keyboard, FAX machine, copier, telephone, mobile phone, phone bezel, radio sender, radio receiver, meter, antenna, light fixture, lighting appliance, transformer, or air conditioner; an article used in building or construction, glazing, roofing, window, window trim, floor, wall panel, door, door trim, countertop, decorative window furnishing or treatment; a treated glass cover for a picture, painting, poster, or display item; a protected graphic; an outdoor or indoor sign; optical lens; ophthalmic lens; corrective ophthalmic lens; implantable ophthalmic lens; refractor; sheath for fluorescent tube; sleeve guard; an article made from a plastic-wood combination; a utility pit cover; shoe lace; cladding or seating for public transportation; cladding or seating for trains, subways, or buses; cladding for satellite dishes; coated helmet or personal protective equipment; coated synthetic or natural textiles; coated photographic film or photographic print; coated painted article; coated dyed article; coated fluorescent article; or coated foam article.
 49. A composition comprising (a) a thermally stable block copolymer comprising resorcinol arylate polyester segments in combination with organic carbonate segments, substantially free of anhydride linkages linking at least two mers of the polymer chain, and (b) at least one auxiliary stabilizer additive selected from the group consisting of 2,2′-(1,4-phenylene)bis(4H-3,1-benzoxazin-4-one) and 1,3-bis[(2-cyano-3,3-diphenylacryloyl)oxy]-2,2-bis[[(2-cyano-3,3-diphenylacryloyl)oxy]methyl]propane.
 50. The composition of claim 49 further comprising at least one auxiliary stabilizer additive selected from the group consisting of a hindered phenol, an epoxide, a phosphite, and phosphorous acid, and mixtures thereof
 51. A unitary or multilayer article comprising the composition of claim
 49. 52. A unitary or multilayer article comprising the composition of claim
 50. 53. The article of claim 51 which is a unitary article.
 54. A multilayer article comprising: a substrate layer comprising at least one thermoplastic polymer, thermoset polymer, cellulosic material, glass, or metal, and at least one coating layer thereon, said coating layer comprising the composition of claim
 49. 55. The article according to claim 54 wherein the substrate comprises at least one homo- or copolymeric aliphatic olefin or functionalized olefin polymer, polycarbonate, polyester or addition polymer of an alkenylaromatic compound.
 56. The article according to claim 55 wherein the substrate comprises at least one polyolefin homopolymer, polyethylene, polypropylene, thermoplastic polyolefin, bisphenol A homo- or copolycarbonate, poly(alkylene terephthalate) or ABS or ASA copolymer.
 57. The article according to claim 54 wherein the coating layer further comprises at least one colorant.
 58. The article according to claim 54 wherein the substrate contains at least one of fillers and colorants.
 59. The article according to claim 54 further comprising at least one intermediate layer disposed between said coating and substrate layers.
 60. The article according to claim 59 wherein at least one intermediate layer is an adhesive layer.
 61. The article according to claim 59 wherein the intermediate layer contains at least one of fillers and colorants.
 62. The article according to claim 54 wherein said multilayer article is further applied to a substrate layer.
 63. The method according to claim 62 wherein the substrate layer comprises at least one homo- or copolymeric aliphatic olefin or functionalized olefin polymer, polycarbonate, polyester or addition polymer of an alkenylaromatic compound.
 64. The article according to claim 51 which is an aircraft, automotive, truck, military vehicle, military aircraft, military water-borne vehicle, scooter, or motorcycle exterior or interior component, panel, quarter panel, rocker panel, trim, fender, door, decklid, trunklid, hood, bonnet, roof, bumper, fascia, grill, mirror housing, pillar applique, cladding, body side molding, wheel cover, hubcap, door handle, spoiler, window frame, headlamp bezel, headlamp, tail lamp, tail lamp housing, tail lamp bezel, license plate enclosure, roof rack, or running board; an enclosure, housing, panel, part, or trim for an outdoor vehicle or device, an electrical or telecommunication device, network interface device, outdoor furniture, aircraft, boat or marine equipment, outboard motor, depth finder, personal water-craft, jet-ski, pool, spa, hot-tub, step, step covering, automatic teller machine (ATM), lawn or garden tractor, lawn mower, tool, lawn or garden tool, sporting equipment, toy, snowmobile, recreational vehicle, golf course marker, or playground equipment; an enclosure, housing, panel, part, or trim for a computer, desk-top computer, portable computer, lap-top computer, palm-held computer, monitor, printer, keyboard, FAX machine, copier, telephone, mobile phone, phone bezel, radio sender, radio receiver, meter, antenna, light fixture, lighting appliance, transformer, or air conditioner; an article used in building or construction, glazing, roofing, window, window trim, floor, wall panel, door, door trim, countertop, decorative window furnishing or treatment; a treated glass cover for a picture, painting, poster, or display item; a protected graphic; an outdoor or indoor sign; optical lens; ophthalmic lens; corrective ophthalmic lens; implantable ophthalmic lens; refractor; sheath for fluorescent tube; sleeve guard; an article made from a plastic-wood combination; a utility pit cover; shoe lace; cladding or seating for public transportation; cladding or seating for trains, subways, or buses; cladding for satellite dishes; coated helmet or personal protective equipment; coated synthetic or natural textiles; coated photographic film or photographic print; coated painted article; coated dyed article; coated fluorescent article; or coated foam article. 